Toward Fast-Charging and Dendritic-Free Li Growth on Natural Graphite Through Intercalation/Conversion on MoS2 Nanosheets

Toward Fast-Charging and Dendritic-Free Li Growth on Natural Graphite Through Intercalation/Conversion on MoS2 Nanosheets

© 2025 Wiley‐VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - (2025) vom: 02. Jan., Seite e2414117
1. Verfasser: Suh, Joo Hyeong (VerfasserIn)
Weitere Verfasser: Han, Sang A, Yang, Soo Young, Lee, Jun Won, Shimada, Yusuke, Lee, Sang-Min, Lee, Jong-Won, Park, Min-Sik, Kim, Jung Ho
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2025
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article anode charging time lithium‐ion batteries molybdenum disulfide natural graphite
Beschreibung
Zusammenfassung:© 2025 Wiley‐VCH GmbH.
During fast-charging, uneven lithium plating on the surface of commercial graphite anode impedes the electrochemical performance of lithium-ion batteries, causing a safety issue. The formation of a passivation layer, the solid-electrolyte interphase (SEI), due to side reactions with the organic electrolyte, correlates with long-term cycling performance under fast-charging conditions, necessitating comprehensive analysis. Herein, it is demonstrated that a molybdenum disulfide (MoS2) coating on natural graphite (NG) modulates the properties of the SEI layer, enabling reduction of the charging time and the enhancement of long-term cycling performance. MoS2 spontaneously transforms into Li2S and Mo nanoclusters through intercalation and conversion with Li+, altering the chemical composition and stability of the SEI layer on the NG, promoting faster Li+ transport, and reducing interfacial resistance. The MoS2-NG anode shows improved fast-charging capability and cycling performance under 3.0 C-charging and 1.0 C-discharging over 300 cycles without compromising energy density. In the full-cell configuration, a charging time of 14.7 min at 80% state of charge is achieved, making it suitable for electric vehicle applications
Beschreibung:Date Revised 03.01.2025
published: Print-Electronic
Citation Status Publisher
ISSN:1521-4095
DOI:10.1002/adma.202414117