Ultra-Narrowband Green-Emitting Transparent Composite Ceramics for Laser-Driven Display
© 2024 Wiley‐VCH GmbH.
Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - (2024) vom: 19. Dez., Seite e2414957 |
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1. Verfasser: | |
Weitere Verfasser: | , , , , , , , , , , |
Format: | Online-Aufsatz |
Sprache: | English |
Veröffentlicht: |
2024
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Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
Schlagworte: | Journal Article laser‐driven projection displays luminescent materials narrowband emitters transparent ceramics |
Zusammenfassung: | © 2024 Wiley‐VCH GmbH. Laser-driven projection displays face a critical challenge in developing laser-excitable and high-performance narrowband green emitters. Herein, new Al2O3-LaMgAl11O19: Mn2+ (Al2O3-LMA: Mn2+) transparent composite ceramics are reported via high-temperature vacuum sintering, which produces a high-color-purity (95.4%) green emission with full width at half maximum of 24 nm and superior thermal and moisture and laser irradiation stability. These are attributed to low electron-phonon couple, weak crystal-field effect, an individual lattice location of Mn2+ activators in high structural rigid host, and the incorporation of a high-thermal-conductivity Al2O3 secondary phase. As a result, the composite ceramics are demonstrated as an attractive color converter with a high external quantum efficiency (38%) and absorption coefficient (53%), which ensures a luminous flux of 2012 lm 40.0 W, a luminous efficacy of 67.7 lm W-1, and a green light conversion efficiency of 20.3% upon blue laser irradiation. This enables to construct a brand-new laser-driven prototype display with a record color gamut beyond Rec.2020 standard (100.8%), outperforming commercial YAG: Ce3+ and β-SiAlON: Eu2+. This exploration in ultra-narrowband green luminescent materials is poised to accelerate the development of "ideal displays" for laser-driven projection display technology |
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Beschreibung: | Date Revised 20.12.2024 published: Print-Electronic Citation Status Publisher |
ISSN: | 1521-4095 |
DOI: | 10.1002/adma.202414957 |