High-Temperature Resistance Photoluminescence Carbonized Polymer Dots Through Equilibrium Bi-Confinement Effects

© 2024 Wiley‐VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - (2024) vom: 13. Dez., Seite e2407811
1. Verfasser: Shen, Yu (VerfasserIn)
Weitere Verfasser: Luo, Chengyang, Chen, Cheng, Zhang, Xinglong, Shi, Minghao, Gu, Zhida, Su, Ruifa, Wang, Yitong, Li, Linpo, Wang, Liangjun, Zhang, Suoying, Huo, Fengwei, Zhang, Weina
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article Al2O3 matrix carbon dots dynamic information encryption high‐temperature photoluminescence
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520 |a Carbon dots are emerging luminescent nanomaterials that have drawn considerable attention due to their abundance, environmental friendliness, and customizable optical properties. However, their susceptibility to temperature-induced vibrational exciton changes and the tendency to thermal quenching of emission have hindered their practical applications. Here, a method is reported for achieving high-temperature photoluminescence carbonized polymer dots (CPDs) through a bi-confinement approach that involves a highly cross-linked polymer network and a rigid Al2O3 matrix. As the temperature increased from 303 to 500 K, the fluorescence and phosphorescence emission intensities of CPDsAl2O3 remained virtually unchanged, with the emission duration exceeding 150 h at 500 K. Additionally, CPDs@Al2O3 composites with different degrees of carbonization exhibit dynamic excitation-dependent photoluminescence properties, which can be patterned for multiple information encryption application. This work provides a concept for designing stable and luminous CPDs under harsh conditions, thus expanding their potential application range 
650 4 |a Journal Article 
650 4 |a Al2O3 matrix 
650 4 |a carbon dots 
650 4 |a dynamic information encryption 
650 4 |a high‐temperature photoluminescence 
700 1 |a Luo, Chengyang  |e verfasserin  |4 aut 
700 1 |a Chen, Cheng  |e verfasserin  |4 aut 
700 1 |a Zhang, Xinglong  |e verfasserin  |4 aut 
700 1 |a Shi, Minghao  |e verfasserin  |4 aut 
700 1 |a Gu, Zhida  |e verfasserin  |4 aut 
700 1 |a Su, Ruifa  |e verfasserin  |4 aut 
700 1 |a Wang, Yitong  |e verfasserin  |4 aut 
700 1 |a Li, Linpo  |e verfasserin  |4 aut 
700 1 |a Wang, Liangjun  |e verfasserin  |4 aut 
700 1 |a Zhang, Suoying  |e verfasserin  |4 aut 
700 1 |a Huo, Fengwei  |e verfasserin  |4 aut 
700 1 |a Zhang, Weina  |e verfasserin  |4 aut 
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773 1 8 |g year:2024  |g day:13  |g month:12  |g pages:e2407811 
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