Topological Transformation and Dimensional Reduction in Multicomponent Metal-Organic Frameworks for Gas Separations

Topological Transformation and Dimensional Reduction in Multicomponent Metal-Organic Frameworks for Gas Separations

© 2024 Wiley‐VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - (2024) vom: 11. Dez., Seite e2414151
1. Verfasser: Li, Hui (VerfasserIn)
Weitere Verfasser: Yang, Huiyue, Pu, Xinya, Xu, Yitang, Zhu, Kai, Xue, Chaozhuang, Huang, Hongliang, Gan, Lei, Yang, Huajun
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article 2D MOFs gas separations multicomponent MOFs self‐assembly
Beschreibung
Zusammenfassung:© 2024 Wiley‐VCH GmbH.
Multicomponent MOFs have offered a wide range of opportunities to harness new properties. However, the synthesis of multicomponent MOFs remains challenging. This work demonstrates the synthesis of a family of multicomponent MOFs by topological transformation from well-established multicomponent partitioned acs (pacs) structures. Such transformation is based on the new understanding on the self-assembly process of pacs MOFs. A key to this understanding is that pacs structures, topologically regarded as the introduction of a pore-partitioning ligand into MOF-235/MIL-88 type framework, are likely to be formed in a layer-pillar-layer fashion in practical reactions. As the π-π interaction between layers and other chemical interactions during the self-assembly process are recognized, the structural transformation can be modulated from 3D pacs structures to 2D interrupted pacs structures (denoted i-pacs). It is especially noteworthy that such dimensional reduction is first observed in metal-organic frameworks and the i-pacs MOFs contain four structural modules and up to five components, which have the highest complexity among 2D MOFs. Interestingly, the i-pacs MOFs have significantly enhanced performance for CO2/N2 separation in comparison with pacs MOFs
Beschreibung:Date Revised 12.12.2024
published: Print-Electronic
Citation Status Publisher
ISSN:1521-4095
DOI:10.1002/adma.202414151