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241121s2024 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202414362
|2 doi
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|a pubmed24n1608.xml
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|a (DE-627)NLM380546914
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|a (NLM)39568295
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|a DE-627
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|a eng
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|a Cao, Honghao
|e verfasserin
|4 aut
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|a Two-Periodic MoS2-Type Metal-Organic Frameworks with Intrinsic Intralayer Porosity for High-Capacity Water Sorption
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|c 2024
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|a Text
|b txt
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Revised 21.11.2024
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|a published: Print-Electronic
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|a Citation Status Publisher
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|a © 2024 Wiley‐VCH GmbH.
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|a 2D metal-organic frameworks (2D-MOFs) are an important class of functional porous materials. However, the low porosity and surface area of 2D-MOFs have greatly limited their functionalities and applications. Herein, the rational synthesis of a class of mos-MOFs with molybdenum disulfide (mos) net based on the assembly of trinuclear metal clusters and 3-connected tripodal organic ligands is reported. The non-crystallographic (3,6)-connected mos net, different from the 3-connected hcb net of graphene, offers abundant intralayer voids courtesy of the split of one node into two. Indeed, mos-MOFs exhibit high apparent Brunauer-Emmett-Teller surface areas, significantly superior to those of other 2D-MOF analogs. Markedly, hydrolytically stable Cr-mos-MOF-1 displays an impressive water vapor uptake of 0.75 g g-1 at 298 K and P/P0 = 0.9, among the highest in 2D-MOFs. The combined water adsorption and X-ray diffraction study reveal the water adsorption mechanisms, suggesting the importance of intralayer porosities of mos-MOFs for high-performance water capture. This study paves the way for a reliable approach to synthesizing 2D-MOFs with high porosity and surface areas for diverse applications
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|a Journal Article
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|a high porosity
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|a metal–organic frameworks
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|a molybdenum disulfide network
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|a reticular chemistry
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|a water adsorption
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|a Shi, Le
|e verfasserin
|4 aut
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|a Xiong, Zhangyi
|e verfasserin
|4 aut
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|a Zhu, Haiyun
|e verfasserin
|4 aut
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|a Wang, Hao
|e verfasserin
|4 aut
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|a Wang, Kun
|e verfasserin
|4 aut
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|a Yang, Zhenning
|e verfasserin
|4 aut
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|a Zhang, Hai-Feng
|e verfasserin
|4 aut
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|a Liu, Lingmei
|e verfasserin
|4 aut
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|a O'Keeffe, Michael
|e verfasserin
|4 aut
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|a Li, Mian
|e verfasserin
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|a Chen, Zhijie
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g (2024) vom: 20. Nov., Seite e2414362
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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|g year:2024
|g day:20
|g month:11
|g pages:e2414362
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|u http://dx.doi.org/10.1002/adma.202414362
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