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241117s2024 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202413325
|2 doi
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|a pubmed24n1604.xml
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|a (DE-627)NLM380353504
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|a (NLM)39548930
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|a DE-627
|b ger
|c DE-627
|e rakwb
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|a eng
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| 100 |
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|a Luo, Yu
|e verfasserin
|4 aut
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|a Engineering Triple-Phase Interfaces with Hierarchical Carbon Nanocages for High-Areal-Capacity All-Solid-State Li-S Batteries
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|c 2024
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Revised 16.11.2024
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|a published: Print-Electronic
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|a Citation Status Publisher
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|a © 2024 Wiley‐VCH GmbH.
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|a All-solid-state lithium-sulfur batteries (ASSLSBs) have garnered widespread attention due to their advantages of high energy density and enhanced safety. However, the typical composite structure composed of solid-state electrolyte (SE), discrete conducting carbon black, and microsized sulfur (μ-S) with long-range Li+/e- conducting path and huge volume changes, suffers from sluggish charge transport and severe electrochemical-mechanical failure. In this work, a unique hierarchical carbon nanocage (hCNC) is applied as a continuous conducting network where nanosized sulfur are confined. Due to the synergistic effects of multi-dimensional (particle, interface, and electrode) structural engineering, this new sulfur-carbon composite cathode (ShCNC39) can achieve uniform distribution of sulfur and carbon, and efficiently constructs triple-phase interfaces, showing enhanced charge-carrier transport and improved electrochemical-mechanical stability. Remarkable cycling performance of 89% after 300 cycles at 0.2 C at 30 °C is realized in ASSLSBs assembled with S@hCNC39. Notably, ASSLSBs achieve an ultrahigh areal capacity of 9.95 mAh cm-2 with stable cycling at 60 °C with high sulfur contents of 40% and high sulfur loadings of 6 mg cm-2. These results provide critical insights into the design of rational sulfur-carbon composites and offer a viable approach to enhance the overall performance of ASSLSBs
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|a Journal Article
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|a all‐solid‐state lithium‐sulfur batteries
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|a electrochemical‐mechanical failure
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|a hierarchical carbon nanocages
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|a multi‐dimensional structural engineering
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|a triple‐phase interface
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1 |
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|a Pan, Siyuan
|e verfasserin
|4 aut
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|a Tian, JingYi
|e verfasserin
|4 aut
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|a Liang, Yali
|e verfasserin
|4 aut
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|a Zhong, Haoyue
|e verfasserin
|4 aut
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|a Ma, Ruqin
|e verfasserin
|4 aut
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|a Gu, Jiabao
|e verfasserin
|4 aut
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|a Wu, Yuqi
|e verfasserin
|4 aut
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|a Zhang, Huiyan
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|4 aut
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|a Lin, Hongxin
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|a Huang, Weilin
|e verfasserin
|4 aut
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|a Deng, Yuxi
|e verfasserin
|4 aut
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|a Su, Yu
|e verfasserin
|4 aut
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1 |
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|a Gong, Zhengliang
|e verfasserin
|4 aut
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|a Huang, Jianyu
|e verfasserin
|4 aut
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|a Hu, Zheng
|e verfasserin
|4 aut
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| 700 |
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|a Yang, Yong
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g (2024) vom: 16. Nov., Seite e2413325
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g year:2024
|g day:16
|g month:11
|g pages:e2413325
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|u http://dx.doi.org/10.1002/adma.202413325
|3 Volltext
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