|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM379742535 |
| 003 |
DE-627 |
| 005 |
20241103232618.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
241103s2024 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202411765
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1589.xml
|
| 035 |
|
|
|a (DE-627)NLM379742535
|
| 035 |
|
|
|a (NLM)39487657
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Zhang, Liangzhu
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Vacancies Engineering in Molybdenum Boride MBene Nanosheets to Activate Room-Temperature Ferromagnetism
|
| 264 |
|
1 |
|c 2024
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 02.11.2024
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status Publisher
|
| 520 |
|
|
|a © 2024 The Author(s). Advanced Materials published by Wiley‐VCH GmbH.
|
| 520 |
|
|
|a The rapid development of low energy dissipation spintronic devices has stimulated the search for air-stable 2D nanomaterials possessing room-temperature ferromagnetism. Here the experimental realization of 2D Mo4/3B2 nanosheets is reported with intrinsic room-temperature ferromagnetic characteristics by vacancy engineering. These nanosheets are synthesized by etching the bulk MAB phase (Mo2/3Y1/3)2AlB2 into Mo4/3B2 nanosheets in ZnCl2 molten salt. The Mo4/3B2 nanosheets show robust intrinsic ferromagnetic properties, with a saturation magnetic moment of 0.044 emu g-1 at 300 K, while vacancy-free MoB MBene exhibits paramagnetism. It is elucidated that the Mo-vacancy defect generates large density of states near the Fermi surface and spontaneously spin-split bands through first-principles calculations, which contributes to the non-zero magnetic moment in Mo4/3B2 nanosheets. This work lays the groundwork for activating the magnetic properties of MBene nanosheets by vacancy engineering, offering the possibilities for development of practical spintronic devices
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a MBene
|
| 650 |
|
4 |
|a molybdenum boride
|
| 650 |
|
4 |
|a nanosheets
|
| 650 |
|
4 |
|a room‐temperature ferromagnetism
|
| 700 |
1 |
|
|a Xing, Shucheng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a He, Tian
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wu, Wei-Bin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, An-Lei
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Guo, Zhoubin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Das, Pratteek
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zheng, Shuanghao
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Ge, Jun-Yi
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Feng, Xinliang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Sun, Zhimei
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wu, Zhong-Shuai
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g (2024) vom: 02. Nov., Seite e2411765
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g year:2024
|g day:02
|g month:11
|g pages:e2411765
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202411765
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|j 2024
|b 02
|c 11
|h e2411765
|