Chiral Nematic Graphene Films with a mesoporous Structure

© 2024 Wiley‐VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - (2024) vom: 31. Okt., Seite e2411955
1. Verfasser: Huang, Haibo (VerfasserIn)
Weitere Verfasser: Wu, Zhong-Shuai, Li, Yixing, Zhang, Xuefeng, Das, Pratteek, Liu, Shouxin, Li, Yudong, Wang, Shaogang, Bao, Xinhe, Cheng, Hui-Ming
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article chemical vapor deposition chiral nematic structure dendrite‐free Na anode electromagnetic shielding graphene film
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520 |a Ordering a crucial material like pure-graphene into the chiral nematic structure can potentially revolutionize the fields of photonics, chiral separation, and energy storage. However, the controlled fabrication of highly ordered graphene films with a long-range chiral nematic mesoporous structure is very challenging and as such, has not been achieved. Here, a chiral-template-directed chemical vapor deposition growth strategy is presented for the precise fabrication of mesoporous chiral nematic graphene films by using nanocrystalline cellulose as templates. It is evidenced that such graphene films possess the left-hand helical ordering, chiral nematic mesoporous structure with adjustable pore sizes (6.4-13.1 nm), tailored pitch, excellent electrical conductivity (556 S cm-1), high specific surface area (1508 m2 g-1) and mechanical flexibility. By coating Na anode with this film, uniform Na plating is achieved with no dendrite formation, resulting from its unique chiral nematic structure and tunable physicochemical properties. The films also achieved impressive thickness-dependent electromagnetic shielding, i.e., 35-63 dB, demonstrating their potentially multi-disciplinary applications 
650 4 |a Journal Article 
650 4 |a chemical vapor deposition 
650 4 |a chiral nematic structure 
650 4 |a dendrite‐free Na anode 
650 4 |a electromagnetic shielding 
650 4 |a graphene film 
700 1 |a Wu, Zhong-Shuai  |e verfasserin  |4 aut 
700 1 |a Li, Yixing  |e verfasserin  |4 aut 
700 1 |a Zhang, Xuefeng  |e verfasserin  |4 aut 
700 1 |a Das, Pratteek  |e verfasserin  |4 aut 
700 1 |a Liu, Shouxin  |e verfasserin  |4 aut 
700 1 |a Li, Yudong  |e verfasserin  |4 aut 
700 1 |a Wang, Shaogang  |e verfasserin  |4 aut 
700 1 |a Bao, Xinhe  |e verfasserin  |4 aut 
700 1 |a Cheng, Hui-Ming  |e verfasserin  |4 aut 
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773 1 8 |g year:2024  |g day:31  |g month:10  |g pages:e2411955 
856 4 0 |u http://dx.doi.org/10.1002/adma.202411955  |3 Volltext 
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