|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM379258684 |
| 003 |
DE-627 |
| 005 |
20241024003027.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
241024s2024 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202408658
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1578.xml
|
| 035 |
|
|
|a (DE-627)NLM379258684
|
| 035 |
|
|
|a (NLM)39439160
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Stone, Aaron E B S
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Photocatalytic Semi-Hydrogenation of Acetylene to Polymer-Grade Ethylene with Molecular and Metal-Organic Framework Cobaloximes
|
| 264 |
|
1 |
|c 2024
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 23.10.2024
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status Publisher
|
| 520 |
|
|
|a © 2024 The Author(s). Advanced Materials published by Wiley-VCH GmbH.
|
| 520 |
|
|
|a The semi-hydrogenation of acetylene in ethylene-rich gas streams is a high-priority industrial chemical reaction for producing polymer-grade ethylene. Traditional thermocatalytic routes for acetylene reduction to ethylene, despite progress, still require high temperatures and high H2 consumption, possess relatively low selectivity, and use a noble metal catalyst. Light-powered strategies are starting to emerge, given that they have the potential to use directly the abundant and sustainable solar irradiation, but are ineffective. Here an efficient, >99.9% selective, visible-light powered, catalytic conversion of acetylene to ethylene is reported. The catalyst is a homogeneous molecular cobaloxime that operates in tandem with a photosensitizer at room temperature and bypasses the use of non-environmentally friendly and flammable H2 gas feed. The reaction proceeds through a cobalt-hydride intermediate with ≈100% conversion of acetylene under competitive (ethylene co-feed) conditions after only 50 min, and with no evolution of H2 or over-hydrogenation to ethane. The cobaloxime is further incorporated as a linker in a metal-organic framework; the result is a heterogeneous catalyst for the conversion of acetylene under competitive (ethylene co-feed) conditions that can be recycled up to six times and remains catalytically active for 48 h, before significant loss of performance is observed
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a acetylene reduction
|
| 650 |
|
4 |
|a hydrogenation
|
| 650 |
|
4 |
|a metal–organic frameworks
|
| 650 |
|
4 |
|a molecular catalysts
|
| 650 |
|
4 |
|a photocatalysis
|
| 700 |
1 |
|
|a Fortunato, Anna
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Xijun
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Saggioro, Edoardo
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Snurr, Randall Q
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Hupp, Joseph T
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Arcudi, Francesca
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Ðorđević, Luka
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g (2024) vom: 22. Okt., Seite e2408658
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g year:2024
|g day:22
|g month:10
|g pages:e2408658
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202408658
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|j 2024
|b 22
|c 10
|h e2408658
|