High-Entropy Layered Oxide Cathode Materials with Moderated Interlayer Spacing and Enhanced Kinetics for Sodium-Ion Batteries

High-Entropy Layered Oxide Cathode Materials with Moderated Interlayer Spacing and Enhanced Kinetics for Sodium-Ion Batteries

© 2024 Wiley‐VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 36(2024), 50 vom: 06. Dez., Seite e2410857
1. Verfasser: Huang, Zefu (VerfasserIn)
Weitere Verfasser: Wang, Shijian, Guo, Xin, Marlton, Frederick, Fan, Yameng, Pang, Wei-Kong, Huang, Tao, Xiao, Jun, Li, Dongfang, Liu, Hao, Gu, Qinfen, Yang, Cheng-Chieh, Dong, Chung-Li, Sun, Bing, Wang, Guoxiu
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article O3‐type structure cathode materials high entropy layered oxides sodium‐ion batteries
Beschreibung
Zusammenfassung:© 2024 Wiley‐VCH GmbH.
Sodium-ion batteries (SIBs) with low cost and environmentally friendly features have recently attracted significant attention for renewable energy storage. Sodium layer oxides stand out as a type of promising cathode material for SIBs owing to their high capacity, good rate performance, and high compatibility for manufacturing. However, the poor cycling stability of layer oxide cathodes due to structure distortion greatly impacts their practical applications. Herein, a high entropy doped Cu, Fe, and Mn-based layered oxide (HE-CFMO), Na0.95Li0.05Mg0.05Cu0.20Fe0.22Mn0.35Ti0.13O2 for high-performance SIBs, is designed. The HE-CFMO cathode possesses high-entropy transition metal (TM) layers with a homogeneous stress distribution, providing a moderated interlayer spacing to maintain the structure stability and enhance Na+ ion diffusion. In addition, Li doping in TM layers increases the Mn valence state, which effectively suppresses John-Teller effect, thus stabilizing the layered structure during cycling. Furthermore, the use of nontoxic and low-cost raw materials benefits future commercialization and reduces the risk of environmental pollution. As a result, the HE-CFMO cathode exhibits a super cycling performance with a 95% capacity retention after 300 cycles. This work provides a promising strategy to improve the structure stability and reaction kinetics of cathode materials for SIBs
Beschreibung:Date Revised 12.12.2024
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1521-4095
DOI:10.1002/adma.202410857