|
|
|
|
| LEADER |
01000caa a22002652 4500 |
| 001 |
NLM379241331 |
| 003 |
DE-627 |
| 005 |
20241105232800.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
241024s2024 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/acs.langmuir.4c02134
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1591.xml
|
| 035 |
|
|
|a (DE-627)NLM379241331
|
| 035 |
|
|
|a (NLM)39437421
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Xin, Jiayu
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Remarkable Enhancement of Bismuth Nanosphere Catalyst Activity for the Conversion of Electrocatalytic CO2 to Formate by Bromine Doping
|
| 264 |
|
1 |
|c 2024
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 05.11.2024
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a Driven by renewable energy, using electrocatalysis to reduce carbon dioxide (CO2) to chemicals is a key technology. It could dim global carbon emissions and promote the carbon cycle. Here, we reported an approach to prepare a Br-doped Bi nanosphere (Br-doped Bi NSP) catalyst for the preparation of formate by electrochemical conversion of CO2. The synthesized Br-doped Bi NSP catalyst manifests high selectivity toward HCOOH. At the applied potential of -0.9 V versus reversible hydrogen electrode, it could achieve a maximum FEHCOOH of 98%. It can remain constant, and the degradation is negligible in continuous electrolysis for 9 h. The excellent CO2 reduction performance is due to the electron richness at the surface of Br-doped Bi NSP induced by the electron transfer between Bi and Br. Density functional theory calculations and in situ attenuated total reflectance-Fourier transform infrared measurements were used to predict the underlying catalyst action's pathway. It can be concluded that the introduction of Br is advantageous to the *OCHO formation, which is conducive to the reduction of the determination step. This research could provide a meaningful view into anion-doping effects to enable effiective electrocatalytic material that selectively reduces carbon dioxide into valuable products
|
| 650 |
|
4 |
|a Journal Article
|
| 700 |
1 |
|
|a Zhao, Xi
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Lihe
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a He, Changliu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Shuai
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Cui
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Liu, Ce
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Jiahong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Ji, Yao
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Xu
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1999
|g 40(2024), 44 vom: 05. Nov., Seite 23189-23197
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
|
| 773 |
1 |
8 |
|g volume:40
|g year:2024
|g number:44
|g day:05
|g month:11
|g pages:23189-23197
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/acs.langmuir.4c02134
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_22
|
| 912 |
|
|
|a GBV_ILN_350
|
| 912 |
|
|
|a GBV_ILN_721
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 40
|j 2024
|e 44
|b 05
|c 11
|h 23189-23197
|