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241022s2024 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202409790
|2 doi
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|a pubmed25n1263.xml
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|a (NLM)39436056
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|a DE-627
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|a eng
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|a Tian, Maofei
|e verfasserin
|4 aut
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|a Bridging to Commercialization
|b Record-Breaking of Ultra-Large and Superior Cyclic Stability Tungsten Oxide Electrochromic Smart Window
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|c 2024
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|a Text
|b txt
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Revised 22.10.2024
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|a published: Print-Electronic
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|a Citation Status Publisher
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|a © 2024 Wiley‐VCH GmbH.
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|a Electrochromic smart windows (ESWs) can significantly reduce energy consumption in buildings, but their cost-effective, large-scale production remains a challenge. In this study, the instability of black phosphorus is leveraged to induce the growth of the tungsten oxide film through its decomposition process, inspired by the 2D material-assisted in situ growth (TAIG) method. This approach results in the preparation of large-scale, high-performance WO3-x·nH2O (n < 2) films. Characterization techniques and DFT calculations confirm efficient regulation of structural water and oxygen vacancies during TAIG preparation. The WO3-x·nH2O films exhibit excellent electrochromic (EC) properties, including high transmittance modulation (74.2%1100 nm), fast switching time (tc = 5.5 s, tb = 3.8 s), high coloration efficiency (124.7 cm2 C-1), and superior cyclic stability (transmittance modulation retained 94.7% after 20 000 cycles). Ultra-large WO3-x·nH2O film are prepared via a simple immersion process, and fabricated into a large-area ESW under facile laboratory conditions, demonstrating the economic and practical feasibility of this approach in industrial-scale production. Operated by the intelligent control circuit, the ESW exhibits remarkable EC properties and cyclic stability This research represents a milestone in improving the performance and industrial-scale production of ESWs, bridging the gap to the commercialization of EC technology
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|a Journal Article
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|a TAIG method
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|a Tungsten oxide
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|a black phosphorus
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|a commercialization
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|a electrochromic smart windows (ESWs)
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|a large‐scale
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|a long cyclic stability
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|a Zheng, Rongzong
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Jia, Chunyang
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g (2024) vom: 22. Okt., Seite e2409790
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnas
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| 773 |
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|g year:2024
|g day:22
|g month:10
|g pages:e2409790
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|u http://dx.doi.org/10.1002/adma.202409790
|3 Volltext
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