Sterically Hindered Organogels with Self-Healing, Impact Response, and High Damping Properties
© 2024 Wiley‐VCH GmbH.
| Veröffentlicht in: | Advanced materials (Deerfield Beach, Fla.). - 1998. - 36(2024), 47 vom: 02. Nov., Seite e2411700 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2024
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| Zugriff auf das übergeordnete Werk: | Advanced materials (Deerfield Beach, Fla.) |
| Schlagworte: | Journal Article hyperbranched fluid impact resistance organogel polymer network steric hinderance |
| Zusammenfassung: | © 2024 Wiley‐VCH GmbH. Organogel materials are vital for impact or shock resistance because of their highly tailored dynamic properties. However, concurrently achieving excellent anti-impact and damping performances, high stability, and self-healing properties is challenging. Herein, a novel intelligent protective organogel (IPO) comprising a dynamic boronic ester containing poly(urethane-urea) as the network skeleton with a matching mesh size is synthesized, the network precisely entraps the hyperbranched fluid used as the bulky solvent via steric hindrance. The IPO exhibits self-healing ability, excellent impact responsiveness (a 1950-fold increase in flow stress under various impact speeds), and energy dissipation (the loss factor >0.8 from 10-4 to 104 Hz). The IPO maintains its dynamic mechanical properties during hot pressing and hydrolysis, exhibiting high stability. Furthermore, the IPO exhibits omnibearing protection. When used as a protective coating, the IPO dissipates the impact force by 87% and 89% of control upon passive and active impact, respectively. When used as a shock pad, it attenuates 91% of the amplitude in the high-frequency vibrations. This study offers a novel perspective on the synthesis of tailored sterically hindered organogel and provides valuable insights into the development of next-generation intelligent protective materials that exhibit impact and vibration resistance |
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| Beschreibung: | Date Revised 25.11.2024 published: Print-Electronic Citation Status PubMed-not-MEDLINE |
| ISSN: | 1521-4095 |
| DOI: | 10.1002/adma.202411700 |