|
|
|
|
| LEADER |
01000naa a22002652 4500 |
| 001 |
NLM37814720X |
| 003 |
DE-627 |
| 005 |
20240927233232.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
240927s2024 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202410947
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1550.xml
|
| 035 |
|
|
|a (DE-627)NLM37814720X
|
| 035 |
|
|
|a (NLM)39328016
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Cao, Jin
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a De-Passivation and Surface Crystal Plane Reconstruction via Chemical Polishing for Highly Reversible Zinc Anodes
|
| 264 |
|
1 |
|c 2024
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 27.09.2024
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status Publisher
|
| 520 |
|
|
|a © 2024 Wiley‐VCH GmbH.
|
| 520 |
|
|
|a Despite the widespread adoption of Zn anodes for aqueous energy storage, the presence of an inherent passivation layer and the polycrystalline interface of commercial Zn foil consistently lead to non-uniform electrodeposition, undermining stability and practicality. Herein, the study introduces a chemically polished Zn metal anode (CP-Zn) fabricated via a simple immersion method. This "chemically polishing" process can effectively remove the interfacial passivation layer (de-passivation), providing ample active sites for plating/stripping and ensuring the uniformly distributed electric field and Zn2+ ion flux. Additionally, selective etching during chemical polishing exposes more (002) crystal planes, promoting homogeneous and smooth zinc deposition while suppressing related side reactions. Demonstrated by CP-Zn anode, the symmetric cell exhibits stable cycling over 4600 h at 1 mA cm-2 and 240 h at 50% depth of discharge (DOD), with a CP-Zn||VO2 full cell maintaining ≈75.3% capacity retention over 1000 cycles at 3 A g-1. This chemically polishing strategy presents a promising avenue for advancing the commercialization of aqueous zinc-ion batteries
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a (002) crystal plane
|
| 650 |
|
4 |
|a chemically polishing
|
| 650 |
|
4 |
|a dendrites
|
| 650 |
|
4 |
|a passivation layer
|
| 650 |
|
4 |
|a zinc‐ion batteries
|
| 700 |
1 |
|
|a Wang, Xu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Qian, Shangshu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Dongdong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Luo, Ding
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Lulu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Qin, Jiaqian
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Xinyu
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yang, Xuelin
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Lu, Jun
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g (2024) vom: 27. Sept., Seite e2410947
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g year:2024
|g day:27
|g month:09
|g pages:e2410947
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202410947
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|j 2024
|b 27
|c 09
|h e2410947
|