High-efficiency leaching process for selective leaching of lithium from spent lithium iron phosphate

Copyright © 2024. Published by Elsevier Ltd.

Bibliographische Detailangaben
Veröffentlicht in:Waste management (New York, N.Y.). - 1999. - 190(2024) vom: 15. Nov., Seite 141-148
1. Verfasser: Li, Guidong (VerfasserIn)
Weitere Verfasser: Chen, Ye, Wu, Mingkun, Xu, Yuzhi, Li, Xiang, Tian, Mengkui
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Waste management (New York, N.Y.)
Schlagworte:Journal Article Cathode material Lithium recovery Selective leaching Spent lithium iron phosphate battery Lithium 9FN79X2M3F Phosphates Hydrogen Peroxide BBX060AN9V mehr... LiFePO4 Iron E1UOL152H7 ferric phosphate N6BAA189V1 Ferric Compounds
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520 |a With the arrival of the scrapping wave of lithium iron phosphate (LiFePO4) batteries, a green and effective solution for recycling these waste batteries is urgently required. Reasonable recycling of spent LiFePO4 (SLFP) batteries is critical for resource recovery and environmental preservation. In this study, mild and efficient, highly selective leaching of lithium from spent lithium iron phosphate was achieved using potassium pyrosulfate (K2S2O7) and hydrogen peroxide (H2O2) as leaching agents. The leaching rates of lithium and iron were 99.83 % and 0.34 %, respectively, at the optimal leaching conditions of 4 vol% 30 wt% H2O2, 0.08 mol/L K2S2O7, 25℃, 5 min, and a solid-liquid ratio of 20 g/L. Meanwhile, the mechanism of the leaching process was explored by thermodynamic, XRD, XPS, FTIR, and SEM analyses. The leaching solution was concentrated and purified, with the addition of potassium carbonate (K2CO3) to convert lithium into lithium carbonate (Li2CO3). A small amount of sulfuric acid (H2SO4) is added to the saline wastewater after precipitation, which can be converted into a leaching agent for recycling after heat treatment. This study provides a sustainable green process for the recovery of lithium iron phosphate and a new idea for resource recovery 
650 4 |a Journal Article 
650 4 |a Cathode material 
650 4 |a Lithium recovery 
650 4 |a Selective leaching 
650 4 |a Spent lithium iron phosphate battery 
650 7 |a Lithium  |2 NLM 
650 7 |a 9FN79X2M3F  |2 NLM 
650 7 |a Phosphates  |2 NLM 
650 7 |a Hydrogen Peroxide  |2 NLM 
650 7 |a BBX060AN9V  |2 NLM 
650 7 |a LiFePO4  |2 NLM 
650 7 |a Iron  |2 NLM 
650 7 |a E1UOL152H7  |2 NLM 
650 7 |a ferric phosphate  |2 NLM 
650 7 |a N6BAA189V1  |2 NLM 
650 7 |a Ferric Compounds  |2 NLM 
700 1 |a Chen, Ye  |e verfasserin  |4 aut 
700 1 |a Wu, Mingkun  |e verfasserin  |4 aut 
700 1 |a Xu, Yuzhi  |e verfasserin  |4 aut 
700 1 |a Li, Xiang  |e verfasserin  |4 aut 
700 1 |a Tian, Mengkui  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Waste management (New York, N.Y.)  |d 1999  |g 190(2024) vom: 15. Nov., Seite 141-148  |w (DE-627)NLM098197061  |x 1879-2456  |7 nnns 
773 1 8 |g volume:190  |g year:2024  |g day:15  |g month:11  |g pages:141-148 
856 4 0 |u http://dx.doi.org/10.1016/j.wasman.2024.09.017  |3 Volltext 
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