Experimental study on high temperature gaseous hydrogen fluoride corrosion of boiler water-cooled wall pipes

Hydrogen fluoride (HF) corrosion of boiler water-cooled wall pipes at high temperature hinders the co-disposal of fluorinated hazardous wastes and coal by combustion. In this paper, common water-cooled wall pipes (15CrMoG and 20G) were utilized to perform gaseous HF corrosion experiments at high tem...

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Veröffentlicht in:Environmental technology. - 1993. - (2024) vom: 21. Sept., Seite 1-16
1. Verfasser: Zhang, Jigang (VerfasserIn)
Weitere Verfasser: Liu, Zijun, Cheng, Kun, Jia, Lianqin, Han, Kuihua
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article Hydrogen fluoride combustion corrosion high temperature metal
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520 |a Hydrogen fluoride (HF) corrosion of boiler water-cooled wall pipes at high temperature hinders the co-disposal of fluorinated hazardous wastes and coal by combustion. In this paper, common water-cooled wall pipes (15CrMoG and 20G) were utilized to perform gaseous HF corrosion experiments at high temperature on a horizontal tube furnace. The effects of temperature on HF corrosion of different water-cooled wall pipes in 0.2% HF were investigated. Corrosion kinetics curve was obtained by calculating the mass increase due to corrosion. The microscopic morphology and physical phase composition of water-cooled wall pipes after HF corrosion were analyzed. The corrosion resistances of the two water-cooled wall pipes decrease with increasing the temperature. The corrosion weight gain curves of 15CrMoG and 20G at 550 ℃ are ΔW1.9144 = 0.2100t and ΔW1.8356 = 0.1344t, respectively. The average corrosion rates of 15CrMoG and 20G are 0.0177 and 0.0125 mg/(cm2·h), respectively. The corrosion resistance of 15CrMoG is superior compared to 20G. The HF corrosion at high temperature consists of non-alternating fluorination and oxidation of the metal matrix. This study is of great significance for the protection of boilers with HF corrosion at high temperature 
650 4 |a Journal Article 
650 4 |a Hydrogen fluoride 
650 4 |a combustion 
650 4 |a corrosion 
650 4 |a high temperature 
650 4 |a metal 
700 1 |a Liu, Zijun  |e verfasserin  |4 aut 
700 1 |a Cheng, Kun  |e verfasserin  |4 aut 
700 1 |a Jia, Lianqin  |e verfasserin  |4 aut 
700 1 |a Han, Kuihua  |e verfasserin  |4 aut 
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773 1 8 |g year:2024  |g day:21  |g month:09  |g pages:1-16 
856 4 0 |u http://dx.doi.org/10.1080/09593330.2024.2405945  |3 Volltext 
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