Forward osmosis membrane with lightweight functionalised multiwall carbon nanotube nanofillers

Thin-film nanocomposite (TFN) membranes with a polyamide (PA) active layer modified with carbon nanotubes (CNTs) hold promise for water desalination and wastewater reuse via forward osmosis (FO). We hypothesise that modifying the PA active layer with hydroxyl-functionalised multi-wall carbon nanotub...

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Publié dans:Environmental technology. - 1993. - 46(2025), 9 vom: 01. Apr., Seite 1507-1518
Auteur principal: Wu, Z (Auteur)
Autres auteurs: Sewwandi, B V N, Chen, Xing, Perera, G, Jayarathna, L, Jayasundara, A C A, Weerasooriya, Rohan
Format: Article en ligne
Langue:English
Publié: 2025
Accès à la collection:Environmental technology
Sujets:Journal Article Multi-walled carbon nanotubes forward osmosis membranes hydroxyl functional groups membrane fouling Nanotubes, Carbon Membranes, Artificial Nylons Wastewater
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520 |a Thin-film nanocomposite (TFN) membranes with a polyamide (PA) active layer modified with carbon nanotubes (CNTs) hold promise for water desalination and wastewater reuse via forward osmosis (FO). We hypothesise that modifying the PA active layer with hydroxyl-functionalised multi-wall carbon nanotubes (f-MWCNTs) will enhance the water flux of the FO membrane while maximising salt rejection. TFN membranes were modified using in situ interfacial polymerisation, with varying f-MWCNT mass content to minimise agglomeration. These modified FO membranes are designated as CTFN-x, where x represents the mass content of f-MWCNTs, ranging from 0.001%, CTFN-1 to 0.008%, CTFN-8 (w/v). The surface properties of CTFN-x were characterised using electron microscopy, atomic force microscopy, and molecular spectroscopy. IR spectroscopic data confirm the successful adherence of f-MWCNTs as a bridging agent between the 1,3-phenylenediamine (MPD) and trimesoyl chloride (TMC) polymers, preserving FO membrane integrity. The CTFN-4 FO membrane shows the highest water flux (29 LMH) and the lowest reverse salt flux (2.90 gHM), attributed to preferential water flow channels in the f-MWCNTs. The integration of f-MWCNTs into the active layer improved water flux, reduced reverse salt flux, and enhanced the antifouling properties of FO membranes 
650 4 |a Journal Article 
650 4 |a Multi-walled carbon nanotubes 
650 4 |a forward osmosis membranes 
650 4 |a hydroxyl functional groups 
650 4 |a membrane fouling 
650 7 |a Nanotubes, Carbon  |2 NLM 
650 7 |a Membranes, Artificial  |2 NLM 
650 7 |a Nylons  |2 NLM 
650 7 |a Wastewater  |2 NLM 
700 1 |a Sewwandi, B V N  |e verfasserin  |4 aut 
700 1 |a Chen, Xing  |e verfasserin  |4 aut 
700 1 |a Perera, G  |e verfasserin  |4 aut 
700 1 |a Jayarathna, L  |e verfasserin  |4 aut 
700 1 |a Jayasundara, A C A  |e verfasserin  |4 aut 
700 1 |a Weerasooriya, Rohan  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Environmental technology  |d 1993  |g 46(2025), 9 vom: 01. Apr., Seite 1507-1518  |w (DE-627)NLM098202545  |x 1479-487X  |7 nnas 
773 1 8 |g volume:46  |g year:2025  |g number:9  |g day:01  |g month:04  |g pages:1507-1518 
856 4 0 |u http://dx.doi.org/10.1080/09593330.2024.2401644  |3 Volltext 
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