|
|
|
|
| LEADER |
01000caa a22002652 4500 |
| 001 |
NLM377669377 |
| 003 |
DE-627 |
| 005 |
20240917234047.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
240916s2024 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1021/acs.chemmater.4c00596
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1536.xml
|
| 035 |
|
|
|a (DE-627)NLM377669377
|
| 035 |
|
|
|a (NLM)39279907
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Doheny, Patrick W
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Low-Temperature Ferromagnetic Order in a Two-Level Layered Co2+ Material
|
| 264 |
|
1 |
|c 2024
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 17.09.2024
|
| 500 |
|
|
|a published: Electronic-eCollection
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2024 The Authors. Published by American Chemical Society.
|
| 520 |
|
|
|a The magnetic properties of a 2D layered material consisting of high-spin Co2+ complexes, [Co(NH3NH2)2(H2O)2Cl2]Cl2 (CoHyd 2 Cl 4 ), have been extensively characterized using electron paramagnetic resonance, magnetic susceptibility, and low-temperature heat capacity measurements. Electron paramagnetic resonance spectroscopy studies suggest that below 50 K, the J = 3/2 orbital triplet state of Co is gradually depopulated in favor of the J = 1/2 spin state, which is dominant below 20 K. In light of this, the magnetic susceptibility has been fitted with a two-level model, indicating that the interactions in this material are much weaker than previously thought. This two-level model is unable to fit the data at low temperatures and, combined with electron paramagnetic resonance spectroscopy, suggests that ferromagnetic interactions between Co2+ cations in the J = 1/2 state become significant approaching 2 K. Heat capacity measurements suggest the emergence of a long-range ordered state below 246 mK, which neutron diffraction confirms to be ferromagnetic
|
| 650 |
|
4 |
|a Journal Article
|
| 700 |
1 |
|
|a Stenning, Gavin B G
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Brookfield, Adam
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Orlandi, Fabio
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Collison, David
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Manuel, Pascal
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Carr, Sam T
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Saines, Paul J
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Chemistry of materials : a publication of the American Chemical Society
|d 1998
|g 36(2024), 17 vom: 10. Sept., Seite 8208-8216
|w (DE-627)NLM098194763
|x 0897-4756
|7 nnns
|
| 773 |
1 |
8 |
|g volume:36
|g year:2024
|g number:17
|g day:10
|g month:09
|g pages:8208-8216
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1021/acs.chemmater.4c00596
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_11
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 36
|j 2024
|e 17
|b 10
|c 09
|h 8208-8216
|