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|a 10.1021/acs.organomet.4c00258
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|a eng
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|a Wade, Casey R
|e verfasserin
|4 aut
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| 245 |
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|a Rh → Sb Interactions Supported by Tris(8-quinolyl)antimony Ligands
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|c 2024
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Revised 14.09.2024
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|a published: Electronic-eCollection
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|a Citation Status PubMed-not-MEDLINE
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| 520 |
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|a © 2024 The Authors. Published by American Chemical Society.
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|a The ligands tris(8-quinolyl)stibine and tris(6-methyl-8-quinolyl)stibine have been synthesized and complexed to rhodium using (MeCN)3RhCl3. The resulting complexes feature an unusual [RhSb]VI core as a result of the formal insertion of the antimony center into one of the Rh-Cl bonds. Computational analysis using density functional theory (DFT) methods reveals that the resulting Rh-Sb σ bond is polarized toward the Rh atom, suggesting a description of this linkage as a Rh → Sb Z-type interaction
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|a Journal Article
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| 700 |
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|a Murphy, Brendan L
|e verfasserin
|4 aut
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| 700 |
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|a Bedajna, Shantabh
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Gabbaï, François P
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Organometallics
|d 1998
|g 43(2024), 17 vom: 09. Sept., Seite 1785-1788
|w (DE-627)NLM098167103
|x 0276-7333
|7 nnns
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| 773 |
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|g volume:43
|g year:2024
|g number:17
|g day:09
|g month:09
|g pages:1785-1788
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|u http://dx.doi.org/10.1021/acs.organomet.4c00258
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