Pyrolysis-induced migration and transformation of heavy metals in sewage sludge containing microplastics

Copyright © 2024. Published by Elsevier Ltd.

Détails bibliographiques
Publié dans:Waste management (New York, N.Y.). - 1999. - 189(2024) vom: 01. Dez., Seite 401-409
Auteur principal: Chang, Xinyi (Auteur)
Autres auteurs: Wu, Pengfei, Chu, Yaozhu, Zhou, Ying, Tang, Yuanyuan
Format: Article en ligne
Langue:English
Publié: 2024
Accès à la collection:Waste management (New York, N.Y.)
Sujets:Journal Article Microplastics Pyrolysis Sewage Sludge Speciation Stabilization of heavy metals Sewage Metals, Heavy Polyvinyl Chloride 9002-86-2
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520 |a Stabilizing heavy metals (HMs) in sewage sludge is urgently needed to facilitate its recycling and reuse. Pyrolysis stands out as a promising method for not only stabilizing these metals but also producing biochar. Our research delves into the migration and transformation of specific HMs (Cr, Mn, Ni, Cu, Zn, As, and Pb) during co-pyrolysis under various conditions, including the presence and absence of microplastics (PVC and PET). We examined different concentrations of these plastics (1 %, 5 %, 10 %, and 15 %) and temperatures (300 °C, 500 °C, and 700 °C). Findings reveal that microplastics, particularly PVC, enhance the migration of Zn and Mn, leading to significant volatilization of Zn and Pb at higher temperatures, peaking at 700 °C. The increase in temperature also markedly influences HM migration, with As showcasing notable loss rates that climbed by 18.0 % and 16.3 % in systems with PET and PVC, respectively, as temperatures soared from 300 °C to 700 °C. Moreover, our speciation analysis indicates that microplastics aid in transforming certain HMs from unstable to more stable forms, suggesting their beneficial role in HM stabilization during pyrolysis. This study significantly enriches our understanding of microplastics' impact on HM behavior in sewage sludge pyrolysis, offering new avenues for pollution control and environmental management strategies 
650 4 |a Journal Article 
650 4 |a Microplastics 
650 4 |a Pyrolysis 
650 4 |a Sewage Sludge 
650 4 |a Speciation 
650 4 |a Stabilization of heavy metals 
650 7 |a Sewage  |2 NLM 
650 7 |a Metals, Heavy  |2 NLM 
650 7 |a Microplastics  |2 NLM 
650 7 |a Polyvinyl Chloride  |2 NLM 
650 7 |a 9002-86-2  |2 NLM 
700 1 |a Wu, Pengfei  |e verfasserin  |4 aut 
700 1 |a Chu, Yaozhu  |e verfasserin  |4 aut 
700 1 |a Zhou, Ying  |e verfasserin  |4 aut 
700 1 |a Tang, Yuanyuan  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Waste management (New York, N.Y.)  |d 1999  |g 189(2024) vom: 01. Dez., Seite 401-409  |w (DE-627)NLM098197061  |x 1879-2456  |7 nnas 
773 1 8 |g volume:189  |g year:2024  |g day:01  |g month:12  |g pages:401-409 
856 4 0 |u http://dx.doi.org/10.1016/j.wasman.2024.08.039  |3 Volltext 
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