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240903s2024 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202407854
|2 doi
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|a pubmed24n1593.xml
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|a (DE-627)NLM377125342
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|a (NLM)39225419
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|a DE-627
|b ger
|c DE-627
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|a eng
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1 |
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|a Lei, Zepeng
|e verfasserin
|4 aut
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|a Dual-Factor-Controlled Dynamic Precursors Enable On-Demand Thermoset Degradation and Recycling
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|c 2024
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Revised 07.11.2024
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2024 Wiley‐VCH GmbH.
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|a Thermosets are well known for their advantages such as high stability and chemical resistance. However, developing sustainable thermosets with degradability and recyclability faces several principal challenges, including reconciling the desired characteristics during service with the recycling and reprocessing properties required at the end of life, establishing efficient methods for large-scale synthesis, and aligning with current manufacturing process. Here a general strategy is presented for the on-demand degradation and recycling of thermosets under mild conditions utilizing dynamic precursors with dual-factor-controlled reversibility. Specifically, dynamic triazine crosslinkers are introduced through dynamic nucleophilic aromatic substitution (SNAr) into the precursor polyols used in polyurethane (PU) synthesis. Upon removal of the catalyst and alcohol, the reversibility of SNAr is deactivated, allowing for the use of standard PU polymerization techniques such as injection molding, casting, and foaming. The resulting cyanurate-crosslinked PUs maintain high stability and diverse mechanical properties of traditional crosslinked PUs, yet offer the advantage of easy on-demand depolymerization for recycling by activating the reversibility of SNAr under specific but mild conditions-a combination of base, alcohol, and mild heat. It is envisioned that this approach, involving the pre-installation of dual-factor-controlled dynamic crosslinkers, can be broadly applied to current thermosetting plastic manufacturing processes, introducing enhanced sustainability
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|a Journal Article
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|a degradation
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|a dynamic covalent chemistry
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|a recycling
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| 650 |
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4 |
|a thermosets
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|a Wang, Zirui
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Jiang, Huan
|e verfasserin
|4 aut
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|a Cahn, Jackson R
|e verfasserin
|4 aut
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|a Chen, Hongxuan
|e verfasserin
|4 aut
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|a Huang, Shaofeng
|e verfasserin
|4 aut
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1 |
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|a Jin, Yinghua
|e verfasserin
|4 aut
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1 |
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|a Wang, Xiaohui
|e verfasserin
|4 aut
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| 700 |
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|a Yu, Kai
|e verfasserin
|4 aut
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| 700 |
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|a Zhang, Wei
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 45 vom: 04. Nov., Seite e2407854
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g volume:36
|g year:2024
|g number:45
|g day:04
|g month:11
|g pages:e2407854
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|u http://dx.doi.org/10.1002/adma.202407854
|3 Volltext
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