|
|
|
|
| LEADER |
01000caa a22002652c 4500 |
| 001 |
NLM376818131 |
| 003 |
DE-627 |
| 005 |
20250306141044.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
240828s2024 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202407249
|2 doi
|
| 028 |
5 |
2 |
|a pubmed25n1255.xml
|
| 035 |
|
|
|a (DE-627)NLM376818131
|
| 035 |
|
|
|a (NLM)39194637
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Fang, Yuqiang
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Above-Room-Temperature Ferroelectricity and Giant Second Harmonic Generation in 1D vdW NbOI3
|
| 264 |
|
1 |
|c 2024
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 03.10.2024
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2024 Wiley‐VCH GmbH.
|
| 520 |
|
|
|a The realization of spontaneous ferroelectricity down to the one-dimensional (1D) limit is both fundamentally intriguing and practically appealing for high-density ferroelectric and nonlinear photonics. However, the 1D vdW ferroelectric materials are not discovered experimentally yet. Here, the first 1D vdW ferroelectric compound NbOI3 with a high Curie temperature TC > 450 K and giant second harmonic generation (SHG) is reported. The 1D crystalline chain structure of the NbOI3 is revealed by cryo-electron microscopy, whereas the 1D ferroelectric order originated from the Nb displacement along the Nb-O chain (b-axis) is confirmed via obvious electrical and ferroelectric hysteresis loops. Impressively, NbOI3 exhibits a giant SHG susceptibility up to 1572 pm V-1 at a fundamental wavelength of 810 nm, and a further enhanced SHG susceptibility of 5582 pm V-1 under the applied hydrostatic pressure of 2.06 GPa. Combing in situ pressure-dependent X-ray diffraction, Raman spectra measurements, and first-principles calculations, it is demonstrated that the O atoms shift along the Nb─O atomic chain under compression, which can lead to the increased Baur distortion of [NbO2I4] octahedra, and hence induces the enhancement of SHG. This work provides a 1D vdW ferroelectric system for developing novel ferroelectronic and photonic devices
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a 1D vdW ferroelectric NbOI3
|
| 650 |
|
4 |
|a high pressure
|
| 650 |
|
4 |
|a second harmonic generation
|
| 700 |
1 |
|
|a Liu, Yue
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yang, Niuzhuang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Gang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a He, Wen
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhou, Xinyi
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Xia, Shian
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Dong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Fu, Jierui
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wang, Jiapeng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Ding, Yang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yu, Ting
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Xu, Chengyan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhen, Liang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Lin, Junhao
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Gou, Gaoyang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Yang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Huang, Fuqiang
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 40 vom: 10. Okt., Seite e2407249
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnas
|
| 773 |
1 |
8 |
|g volume:36
|g year:2024
|g number:40
|g day:10
|g month:10
|g pages:e2407249
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202407249
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 36
|j 2024
|e 40
|b 10
|c 10
|h e2407249
|