Spatial confined synthesis of submicron Fe-MoS2 with abundant surface cationic groups and sulfur vacancies for enhanced peroxymonosulfate activation
The widespread use of emerging refractory organic contaminants poses a significant threat to human health, prompting the need for a cost-effective and efficient removal strategy. While the iron ions/PMS system effectively removes organic pollutants, slow Fe3+ to Fe2+ transformation hampers its effic...
| Veröffentlicht in: | Environmental technology. - 1993. - 46(2025), 10 vom: 30. Apr., Seite 1561-1572 |
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| 1. Verfasser: | |
| Weitere Verfasser: | , , , , , , , |
| Format: | Online-Aufsatz |
| Sprache: | English |
| Veröffentlicht: |
2025
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| Zugriff auf das übergeordnete Werk: | Environmental technology |
| Schlagworte: | Journal Article Molybdenum disulfide heterogeneous iron catalysts peroxymonosulfate spatial confined synthesis Sulfur 70FD1KFU70 22047-43-4 Iron E1UOL152H7 mehr... |
| Zusammenfassung: | The widespread use of emerging refractory organic contaminants poses a significant threat to human health, prompting the need for a cost-effective and efficient removal strategy. While the iron ions/PMS system effectively removes organic pollutants, slow Fe3+ to Fe2+ transformation hampers its efficiency, and the homogeneous distribution of iron ions complicates separation, resulting in secondary sludge pollution. Herein, we developed a novel submicron Fe-MoS2 (S-Fe-MoS2) catalyst with abundant surface cationic groups and sulfur vacancy through a cationic polyacrylamide aerogels (CPAMA) confined hydrothermal synthesis strategy. These features promote active site exposure, enhance reactant adsorption, and accelerate electron transfer between Mo and Fe sites, improving catalytic kinetics and promoting Fe3+/Fe2+ cycle for PMS activation. As a result, the S-Fe-MoS2/PMS system exhibited a high catalytic rate constant (kobs) of 0.32 min-1, in the degradation of 4-chlorophenol (4-CP), 1.5 times higher than that of the conventional Fe-MoS2/PMS system. It also achieved 82.9% total organic carbon (TOC) degradation within 60 min. Additionally, it possessed similar degradation performance for various organic pollutants, along with remarkable reusability (four cycles) and broad pH adaptability (2-8), indicating significant potential for widespread application. This study provided a new way for developing advanced heterogeneous catalysts with high efficiency for water treatment |
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| Beschreibung: | Date Completed 23.04.2025 Date Revised 23.04.2025 published: Print-Electronic Citation Status MEDLINE |
| ISSN: | 1479-487X |
| DOI: | 10.1080/09593330.2024.2391076 |