Ultrahigh Single Au Atoms Loaded Porous Aromatic Frameworks for Enhanced Photocatalytic Hydrogen Evolution

Ultrahigh Single Au Atoms Loaded Porous Aromatic Frameworks for Enhanced Photocatalytic Hydrogen Evolution

© 2024 Wiley‐VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 36(2024), 41 vom: 16. Okt., Seite e2404791
1. Verfasser: Yang, Yuting (VerfasserIn)
Weitere Verfasser: Xiao, Yang, Jiang, Li, Li, Jiahui, Li, Jialu, Jia, Jiangtao, Yavuz, Cafer T, Cui, Fengchao, Jing, Xiaofei, Zhu, Guangshan
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article green hydrogen heterogeneous catalysis porous materials single‐atom catalysts water splitting
Beschreibung
Zusammenfassung:© 2024 Wiley‐VCH GmbH.
Supported single-atom catalysts (SACs) are promising in heterogeneous catalysis because of their atom economy, unusual transformations, and mechanistic clarity. The metal SAs loading, however, limits the catalytic efficiency. Herein, an in situ pre-metallated monomer-based preparation strategy is shown to achieve ultrahigh Au SAs loading in catalyst formations. The polymerization of single-atom loaded monomers yield a new porous aromatic framework (PAF-164) with Au SAs loading up to a record high 45.3 wt.%. SACs of Au-PAFs exhibit excellent photocatalytic activity in hydrogen (H2) evolution, and the H2 evolution rate of Au100%-SAs-PAF-164 can reach 4.82 mmol g-1 h-1 with great recyclability
Beschreibung:Date Revised 10.10.2024
published: Print-Electronic
Citation Status PubMed-not-MEDLINE
ISSN:1521-4095
DOI:10.1002/adma.202404791