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240710s2024 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.4c01653
|2 doi
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|a eng
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| 100 |
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|a Li, Zhanbo
|e verfasserin
|4 aut
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|a On-Surface Synthesis of Five-Membered Copper Metallacycles Using Terminal Alkynes
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|c 2024
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|a Text
|b txt
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Revised 23.07.2024
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a We present our studies on the adsorption, deprotonation, and reactions of 4,4″-diethynyl-1,1':4',1″-terphenyl on Cu(111) under ultrahigh-vacuum conditions using scanning tunneling microscopy combined with density functional theory calculations. Sequential annealing treatments induce deprotonation of pristine molecules followed by chemical reactions, resulting in branched nanostructures. Within the nanostructures, a previously unreported, double-spot linkage is observed. Our density functional theory calculations unravel that this linkage corresponds to a five-membered copper metallacycle
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|a Journal Article
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|a Wang, Yule
|e verfasserin
|4 aut
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|a Zhang, Liding
|e verfasserin
|4 aut
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|a Chen, Zhi
|e verfasserin
|4 aut
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|a Barth, Johannes V
|e verfasserin
|4 aut
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|a Li, Juan
|e verfasserin
|4 aut
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| 700 |
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|a Lin, Tao
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 40(2024), 29 vom: 23. Juli, Seite 15214-15219
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|g volume:40
|g year:2024
|g number:29
|g day:23
|g month:07
|g pages:15214-15219
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|u http://dx.doi.org/10.1021/acs.langmuir.4c01653
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