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240706s2024 xx |||||o 00| ||eng c |
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|a 10.1016/j.wasman.2024.06.027
|2 doi
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|a pubmed25n1247.xml
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|a eng
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| 100 |
1 |
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|a Wu, Li-Jun
|e verfasserin
|4 aut
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|a Conversion and fate of waste Li-ion battery electrolyte in a two-stage thermal treatment process
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|c 2024
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Completed 10.08.2024
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|a Date Revised 10.08.2024
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a Copyright © 2024 Elsevier Ltd. All rights reserved.
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|a Disposal of electrolytes from waste lithium-ion batteries (LIBs) has gained much more attention with the growing application of LIBs, yet handling spent electrolyte is challengeable due to its high toxicity and the lack of established methods. In this study, a novel two-stage thermal process was developed for treating residual electrolytes resulted from spent lithium-ion batteries. The conversion of fluorophosphate and organic matter in oily electrolyte during low-temperature rotation distillation was investigated. The distribution and migration of the concentrated electrolytes were studied and the corresponding reaction mechanisms were elucidated. Additionally, the influence of alkali on the fixation of fluorine and phosphate was further examined. The results indicated that hydrolyzed carbonate esters and lithium in the electrolyte could combine to form Li2CO3 and the hydrolysable hexafluorophosphate was proven to be stable in the concentrated electrolyte (45 rpm/85 °C, 30 min). It was found that CO2, CO, CH4, and H2 were the primary pyrolysis gases, while the pyrolysis oil consisted of extremely flammable substances formed by the dissociation and recombination of chemical bonds in the electrolyte solvent. After pyrolysis at 300 °C, fluorine and phosphate were present in the form of sodium fluoride and sodium phosphate. The stability of the residue was enhanced, and the environmental risk was reduced. By adding alkali (KOH/Ca(OH)2, 20 %), hexafluorophosphate in the electrolyte was transformed into fluoride and phosphate in the residue, thereby reducing the device's corrosion from fluorine-containing gas. This study provides a viable approach for managing the residual electrolyte in the waste lithium battery recovery process
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|a Journal Article
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|a Distillation
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|a Pyrolysis
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|a Spent electrolyte
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|a Two-stage thermal treatment
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|a Waste Li-ion batteries
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|a Lithium
|2 NLM
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|a 9FN79X2M3F
|2 NLM
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| 650 |
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|a Electrolytes
|2 NLM
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| 700 |
1 |
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|a Zhang, Fu-Shen
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhang, Zhi-Yuan
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhang, Cong-Cong
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Waste management (New York, N.Y.)
|d 1999
|g 187(2024) vom: 01. Okt., Seite 1-10
|w (DE-627)NLM098197061
|x 1879-2456
|7 nnas
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| 773 |
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|g volume:187
|g year:2024
|g day:01
|g month:10
|g pages:1-10
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|u http://dx.doi.org/10.1016/j.wasman.2024.06.027
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