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240627s2024 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202406807
|2 doi
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|a pubmed24n1516.xml
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|a eng
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| 100 |
1 |
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|a Cheng, Lei
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Toward Functionality and Deactivation of Metal-Single-Atom in Heterogeneous Photocatalysts
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|c 2024
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|a Text
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Revised 28.08.2024
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2024 Wiley‐VCH GmbH.
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|a Single-atom heterogeneous catalysts (SAHCs) provide an enticing platform for understanding catalyst structure-property-performance relationships. The 100% atom utilization and adjustable local coordination configurations make it easy to probe reaction mechanisms at the atomic level. However, the progressive deactivation of metal-single-atom (MSA) with high surface energy leads to frequent limitations on their commercial viability. This review focuses on the atomistic-sensitive reactivity and atomistic-progressive deactivation of MSA to provide a unifying framework for specific functionality and potential deactivation drivers of MSA, thereby bridging function, purpose-modification structure-performance insights with the atomistic-progressive deactivation for sustainable structure-property-performance accessibility. The dominant functionalization of atomically precise MSA acting on properties and reactivity encompassing precise photocatalytic reactions is first systematically explored. Afterward, a detailed analysis of various deactivation modes of MSA and strategies to enhance their durability is presented, providing valuable insights into the design of SAHCs with deactivation-resistant stability. Finally, the remaining challenges and future perspectives of SAHCs toward industrialization, anticipating shedding some light on the next stage of atom-economic chemical/energy transformations are presented
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|a Journal Article
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|a Review
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|a deactivation
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|a functionality
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|a single‐atom heterogeneous catalysts
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| 650 |
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|a stability
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| 650 |
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|a structure–property–performance
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| 700 |
1 |
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|a Wu, Qiaolin
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Sun, Hanjun
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Tang, Yawen
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Xiang, Quanjun
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 35 vom: 27. Aug., Seite e2406807
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g volume:36
|g year:2024
|g number:35
|g day:27
|g month:08
|g pages:e2406807
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| 856 |
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|u http://dx.doi.org/10.1002/adma.202406807
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