Ultra-high Performance Thermochromic Polymers via a Solid-solid Phase Transition Mechanism and Their Applications

© 2024 Wiley‐VCH GmbH.

Détails bibliographiques
Publié dans:Advanced materials (Deerfield Beach, Fla.). - 1998. - 36(2024), 36 vom: 24. Sept., Seite e2405430
Auteur principal: Soo, Xiang Yun Debbie (Auteur)
Autres auteurs: Zhang, Danwei, Tan, Sze Yu, Chong, Yi Ting, Hui, Hui Kim, Sng, Anqi, Wei, Fengxia, Suwardi, Ady, Png, Zhuang Mao, Zhu, Qiang, Xu, Jianwei
Format: Article en ligne
Langue:English
Publié: 2024
Accès à la collection:Advanced materials (Deerfield Beach, Fla.)
Sujets:Journal Article 3D‐printing smart windows solid‐solid phase transition thermal energy storage thermochromism thermoelectric devices thermo‐regulation
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520 |a Thermochromic materials are substances that change color in response to temperature variations. Today, sustainability concerns are the main drivers of thermochromic research, with smart, energy-efficient windows being one of the primary applications. While vanadium oxides and leuco dyes are traditionally the main thermochromic materials, hydrogels operating based on change of solvation have risen as some of the most promising materials due to their high optical transparency and good solar modulating abilities. In this work, a distinct mechanism for thermochromism arising from the crystalline solid to amorphous solid polymer transition, with a corresponding transition from an opaque state to a transparent state is disclosed. Both ultra-high optical transparency (Tlum up to 99%) and ultra-high solar modulation (ΔTsolar up to 87%) are observed. The transition temperature is tunable from 11 to 61 °C by tuning the polymer structure. When incorporated into applications such as greenhouse materials and thermoelectric devices, significant performance enhancement is observed, due to the thermochromic material functioning as a thermal valve, speeding up solar heat absorbance while inhibiting the cooling process via its phase transition 
650 4 |a Journal Article 
650 4 |a 3D‐printing 
650 4 |a smart windows 
650 4 |a solid‐solid phase transition 
650 4 |a thermal energy storage 
650 4 |a thermochromism 
650 4 |a thermoelectric devices 
650 4 |a thermo‐regulation 
700 1 |a Zhang, Danwei  |e verfasserin  |4 aut 
700 1 |a Tan, Sze Yu  |e verfasserin  |4 aut 
700 1 |a Chong, Yi Ting  |e verfasserin  |4 aut 
700 1 |a Hui, Hui Kim  |e verfasserin  |4 aut 
700 1 |a Sng, Anqi  |e verfasserin  |4 aut 
700 1 |a Wei, Fengxia  |e verfasserin  |4 aut 
700 1 |a Suwardi, Ady  |e verfasserin  |4 aut 
700 1 |a Png, Zhuang Mao  |e verfasserin  |4 aut 
700 1 |a Zhu, Qiang  |e verfasserin  |4 aut 
700 1 |a Xu, Jianwei  |e verfasserin  |4 aut 
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773 1 8 |g volume:36  |g year:2024  |g number:36  |g day:24  |g month:09  |g pages:e2405430 
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