|
|
|
|
| LEADER |
01000caa a22002652 4500 |
| 001 |
NLM373875541 |
| 003 |
DE-627 |
| 005 |
20240829232812.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
240620s2024 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202404932
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1516.xml
|
| 035 |
|
|
|a (DE-627)NLM373875541
|
| 035 |
|
|
|a (NLM)38899577
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Guillen Campos, Jesus
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Photoactivation of Millimeters Thick Liquid Crystal Elastomers with Broadband Visible Light Using Donor-Acceptor Stenhouse Adducts
|
| 264 |
|
1 |
|c 2024
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 28.08.2024
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2024 The Author(s). Advanced Materials published by Wiley‐VCH GmbH.
|
| 520 |
|
|
|a Light-responsive liquid crystal elastomers (LCEs) are stimuli-responsive materials that facilitate the conversion of light energy into a mechanical response. In this work, a novel polysiloxane-based LCE with donor-acceptor Stenhouse adduct (DASA) side-chains is synthesized using a late-stage functionalization strategy. It is demonstrated that this approach does not compromise the molecular alignment observed in the traditional Finkelmann method. This easy, single-batch process provides a robust platform to access well-aligned, light-responsive LCE films with thickness ranging from 400 µm to a 14-layer stack that is 5 mm thick. Upon irradiation with low-intensity broadband visible light (100-200 mW cm-2), these systems undergo 2D planar actuation and complete bleaching. Conversely, exposure to higher-intensity visible light induces bending followed by contraction (300 mW cm-2). These processes are repeatable over several cycles. Finally, it is demonstrated how light intensity and the resulting heat generation influences the photothermal stationary state equilibrium of DASA, thereby controlling its photoresponsive properties. This work establishes the groundwork for advancement of LCE-based actuators beyond thin film and UV-light reliant systems
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a donor–acceptor stenhouse adducts
|
| 650 |
|
4 |
|a liquid crystal elastomers
|
| 650 |
|
4 |
|a photomechanical response
|
| 650 |
|
4 |
|a photoswitches
|
| 650 |
|
4 |
|a visible light actuation
|
| 700 |
1 |
|
|a Tobin, Cassidy
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Sandlass, Sara
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Park, Minwook
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wu, Yuhang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Gordon, Michael
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Read de Alaniz, Javier
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 35 vom: 13. Aug., Seite e2404932
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:36
|g year:2024
|g number:35
|g day:13
|g month:08
|g pages:e2404932
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202404932
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 36
|j 2024
|e 35
|b 13
|c 08
|h e2404932
|