|
|
|
|
| LEADER |
01000caa a22002652 4500 |
| 001 |
NLM373875517 |
| 003 |
DE-627 |
| 005 |
20240815232355.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
240620s2024 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202406257
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1502.xml
|
| 035 |
|
|
|a (DE-627)NLM373875517
|
| 035 |
|
|
|a (NLM)38899574
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Huang, Jiangtao
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Interfacial Biomacromolecular Engineering Toward Stable Ah-Level Aqueous Zinc Batteries
|
| 264 |
|
1 |
|c 2024
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 15.08.2024
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2024 Wiley‐VCH GmbH.
|
| 520 |
|
|
|a Interfacial instability within aqueous zinc batteries (AZBs) spurs technical obstacles including parasitic side reactions and dendrite failure to reach the practical application standards. Here, an interfacial engineering is showcased by employing a bio- derived zincophilic macromolecule as the electrolyte additive (0.037 wt%), which features a long-chain configuration with laterally distributed hydroxyl and sulfate anion groups, and has the propensity to remodel the electric double layer of Zn anodes. Tailored Zn2+-rich compact layer is the result of their adaptive adsorption that effectively homogenizes the interfacial concentration field, while enabling a hybrid nucleation and growth mode characterized as nuclei-rich and space-confined dense plating. Further resonated with curbed corrosion and by-products, a dendrite-free deposition morphology is achieved. Consequently, the macromolecule-modified zinc anode delivers over 1250 times of reversible plating/stripping at a practical area capacity of 5 mAh cm-2, as well as a high zinc utilization rate of 85%. The Zn//NH4V4O10 pouch cell with the maximum capacity of 1.02 Ah can be steadily operated at 71.4 mA g-1 (0.25 C) with 98.7% capacity retained after 50 cycles, which demonstrates the scale-up capability and highlights a "low input and high return" interfacial strategy toward practical AZBs
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a Ah‐level pouch cell
|
| 650 |
|
4 |
|a aqueous zinc batteries
|
| 650 |
|
4 |
|a biomacromolecule
|
| 650 |
|
4 |
|a electric double layer
|
| 650 |
|
4 |
|a nucleation model
|
| 700 |
1 |
|
|a Zhong, Yunpeng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Fu, Hongwei
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhao, Yunxiang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Li, Shenglong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Xie, Yiman
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Hao
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Lu, Bingan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chen, Lina
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Liang, Shuquan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhou, Jiang
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 33 vom: 15. Aug., Seite e2406257
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:36
|g year:2024
|g number:33
|g day:15
|g month:08
|g pages:e2406257
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202406257
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 36
|j 2024
|e 33
|b 15
|c 08
|h e2406257
|