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240619s2024 xx |||||o 00| ||eng c |
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|a 10.1021/acs.langmuir.4c00831
|2 doi
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|a eng
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|a Zhang, Binyuan
|e verfasserin
|4 aut
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|a Constructing the Interconnected and Hierarchical Nanoarchitectonics in Coal-Derived Carbon for High-Performance Supercapacitor
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|c 2024
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|a Text
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|a ƒaComputermedien
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|a Date Revised 02.07.2024
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Because of the deep and zigzag microporous structure, porous carbon materials exhibit inferior capacitive performance and sluggish electrochemical kinetics for supercapacitor electrode materials. Herein, a single-step carbonation and activation approach was utilized to synthesize coal-based porous carbon with an adjustable pore structure, using CaO as a hard template, KOH as an activator, and oxidized coal as precursors to carbon. The obtained sample possesses an interconnected and hierarchical porous structure, higher SSA (1060 m2 g-1), suitable mesopore volume (0.25 cm3 g-1), and abundant surface heteroatomic functional groups. Consequently, the synthesized carbon exhibits an exceptionally high specific capacitance of 323 F g-1 at 1 A g-1, along with 80.3% capacitance retention at 50 A g-1. The assembled two-electrode configuration demonstrates a remarkable capacitance retention of up to 95% and achieves Coulombic efficiency of nearly 100% with 10,000 cycles in a 6 M KOH electrolyte. Furthermore, the Zn-ion hybrid capacitor also exhibits a specific capacity of up to 139.1 mA h g-1 under conditions of 0.2 A g-1. This work offers a simple method in preparation of coal-based porous carbon with controllable pore structure
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|a Journal Article
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|a Feng, Xia
|e verfasserin
|4 aut
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|a Ma, Rui
|e verfasserin
|4 aut
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|a Sheng, Rui
|e verfasserin
|4 aut
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|a Wang, Danting
|e verfasserin
|4 aut
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|a Chen, Feifei
|e verfasserin
|4 aut
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|a Wang, Yuanyuan
|e verfasserin
|4 aut
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|a Xu, Mengjiao
|e verfasserin
|4 aut
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|a Ai, Lili
|e verfasserin
|4 aut
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|a Guo, Nannan
|e verfasserin
|4 aut
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|a Wang, Luxiang
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 40(2024), 26 vom: 02. Juli, Seite 13467-13475
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:40
|g year:2024
|g number:26
|g day:02
|g month:07
|g pages:13467-13475
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|u http://dx.doi.org/10.1021/acs.langmuir.4c00831
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