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240615s2024 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202404682
|2 doi
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|a eng
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| 100 |
1 |
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|a Wang, Jie
|e verfasserin
|4 aut
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| 245 |
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|a Ultrahigh Electrobending Deformation in Lead-Free Piezoelectric Ceramics via Defect Concentration Gradient Design
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|c 2024
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|a Text
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Revised 15.08.2024
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2024 Wiley‐VCH GmbH.
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|a Recent breakthroughs in defect-engineered lead-free piezoelectric ceramics have reported remarkable electrostrain values, surpassing the limit of lattice distortion. This has aroused wide concern on bending deformation and the associated underlying mechanism. Herein, via designing lead-free piezoelectric ceramics with varying volatilization characteristics, it is uncovered that the ultrahigh electrobending deformation is primarily attributed to a large strain gradient induced by unevenly distributed defect dipoles. In 0.5 mm thick Sr/Sn co-doped potassium sodium niobate ceramics featuring volatile K/Na elements, the inherent bipolar electrostrain value can reach 0.3% at 20 kV cm-1 due to the existence of defect dipoles, while the gradient distribution of defect dipole generates significant bending displacement, amplifying apparent electrostrain value to 1.1%. Notably, nonvolatile Ba0.99TiO2.99 ceramic with homogeneous defect dipole distribution does not present electrobending. Of particular interest is that the electrobending phenomenon can be observed through introducing a defect dipole gradient into barium titanate ceramic. A monolayer ceramic with defect dipole gradient can generate large tip displacement (±1.5 mm) in cantilever structure, demonstrating its promising potential in precise positioning. This study delves into the underlying mechanism driving electrobending deformation and its impact on the apparent electrostrain measurement in defect-engineered piezoelectric ceramics, providing fresh perspectives for the development of piezoelectric bending actuators
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|a Journal Article
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|a defect dipole
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|a electrobending
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|a lead‐free piezoelectric ceramic
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|a piezoelectric actuator
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1 |
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|a Wang, Binquan
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhang, Hongjie
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Zhang, Shujun
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Guo, Yiping
|e verfasserin
|4 aut
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| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 33 vom: 13. Aug., Seite e2404682
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
1 |
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|g volume:36
|g year:2024
|g number:33
|g day:13
|g month:08
|g pages:e2404682
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| 856 |
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|u http://dx.doi.org/10.1002/adma.202404682
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