Sludge reduction and hydrogen production in a microbial photoelectrochemical cell with a g-C3N4/CQDs/BiOBr composite photocathode

Hydrogen (H2) remains a pivotal clean energy source, and the emergence of Solar-powered Microbial Photoelectrochemical Cells (MPECs) presents promising avenues for H2 production while concurrently aiding organic matter degradation. This study introduces an MPEC system employing a g-C3N4/CQDs/BiOBr p...

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Veröffentlicht in:Environmental technology. - 1993. - (2024) vom: 11. Juni, Seite 1-14
1. Verfasser: Li, Yue (VerfasserIn)
Weitere Verfasser: Zhao, Jinyu, Lin, Lili, Li, Jing, Gao, Ziru, Li, Jiayi, Gu, Yingying
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Environmental technology
Schlagworte:Journal Article H2 production Microbial photoelectrochemical cell environmental protection g-C3N4/CQDs/BiOBr photocathode sludge reduction
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520 |a Hydrogen (H2) remains a pivotal clean energy source, and the emergence of Solar-powered Microbial Photoelectrochemical Cells (MPECs) presents promising avenues for H2 production while concurrently aiding organic matter degradation. This study introduces an MPEC system employing a g-C3N4/CQDs/BiOBr photocathode and a bioanode, successfully achieving simultaneous H2 production and sludge reduction. The research highlights the effective formation of a Z-type heterojunction in the g-C3N4/CQDs/BiOBr photocathode, substantially enhancing the photocurrent response under light conditions. Operating at - 0.4 V versus RHE, it demonstrated a current density of - 3.25 mA·cm-2, surpassing that of g-C3N4/BiOBr (-2.25 mA·cm-2) by 1.4 times and g-C3N4 (-2.04 mA·cm-2) by 1.6 times. When subjected to visible light irradiation and a 0.8 V applied bias voltage, the MPEC system achieved a current density of 1.0 mA·cm-2. The cumulative H2 production of the MPEC system reached 8.9 mL, averaging a production rate of 0.13 mL·h-1. In the anode chamber, the degradation rates of total chemical oxygen demand (TCOD), soluble chemical oxygen demand (SCOD), total suspended solids (TSS), volatile suspended solids (VSS), proteins, polysaccharides, and volatile fatty acids (VFA) in the sludge were recorded at 57.18%, 82.64%, 64.98%, 86.39%, 42.81%, 67.34%, and 29.01%, respectively 
650 4 |a Journal Article 
650 4 |a H2 production 
650 4 |a Microbial photoelectrochemical cell 
650 4 |a environmental protection 
650 4 |a g-C3N4/CQDs/BiOBr photocathode 
650 4 |a sludge reduction 
700 1 |a Zhao, Jinyu  |e verfasserin  |4 aut 
700 1 |a Lin, Lili  |e verfasserin  |4 aut 
700 1 |a Li, Jing  |e verfasserin  |4 aut 
700 1 |a Gao, Ziru  |e verfasserin  |4 aut 
700 1 |a Li, Jiayi  |e verfasserin  |4 aut 
700 1 |a Gu, Yingying  |e verfasserin  |4 aut 
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773 1 8 |g year:2024  |g day:11  |g month:06  |g pages:1-14 
856 4 0 |u http://dx.doi.org/10.1080/09593330.2024.2361486  |3 Volltext 
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