|
|
|
|
| LEADER |
01000caa a22002652 4500 |
| 001 |
NLM373260199 |
| 003 |
DE-627 |
| 005 |
20240829232738.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
240606s2024 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202406682
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1516.xml
|
| 035 |
|
|
|a (DE-627)NLM373260199
|
| 035 |
|
|
|a (NLM)38837816
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Guo, Linchuan
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Ceria-Optimized Oxygen-Species Exchange in Hierarchical Bimetallic Hydroxide for Electrocatalytic Water Oxidation
|
| 264 |
|
1 |
|c 2024
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 28.08.2024
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2024 Wiley‐VCH GmbH.
|
| 520 |
|
|
|a The utilization of rare earth elements to regulate the interaction between catalysts and oxygen-containing species holds promising prospects in the field of oxygen electrocatalysis. Through structural engineering and adsorption regulation, it is possible to achieve high-performance catalytic sites with a broken activity-stability tradeoff. Herein, this work fabricates a hierarchical CeO2/NiCo hydroxide for electrocatalytic oxygen evolution reaction (OER). This material exhibits superior overpotentials and enhanced stability. Multiple potential-dependent experiments reveal that CeO2 promotes oxygen-species exchange, especially OH- ions, between catalyst and environment, thereby optimizing the redox transformation of hydroxide and the adsorption of oxygen-containing intermediates during OER. This is attributed to the reduction in the adsorption energy barrier of Ni to *OH facilitated by CeO2, particularly the near-interfacial Ni sites. The less-damaging adsorbate evolution mechanism and the CeO2 hierarchical shell significantly enhance the structural robustness, leading to exceptional stability. Additionally, the observed "self-healing" phenomenon provides further substantiation for the accelerated oxygen exchange. This work provides a neat strategy for the synthesis of ceria-based complex hollow electrocatalysts, as well as an in-depth insight into the co-catalytic role of CeO2 in terms of oxygen transfer
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a ceria‐based materials
|
| 650 |
|
4 |
|a complex hollow structures
|
| 650 |
|
4 |
|a electrocatalysis
|
| 650 |
|
4 |
|a oxygen evolution reaction
|
| 650 |
|
4 |
|a self‐healing
|
| 650 |
|
4 |
|a surface adsorption
|
| 700 |
1 |
|
|a Zhang, Zhuang
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Mu, Zhaori
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Da, Pengfei
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a An, Li
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Shen, Wei
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Hou, Yichao
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Xi, Pinxian
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Yan, Chun-Hua
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 35 vom: 01. Aug., Seite e2406682
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:36
|g year:2024
|g number:35
|g day:01
|g month:08
|g pages:e2406682
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202406682
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 36
|j 2024
|e 35
|b 01
|c 08
|h e2406682
|