Recent Progress of Fluorinated Conjugated Polymers

© 2024 Wiley‐VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 36(2024), 32 vom: 03. Aug., Seite e2403961
1. Verfasser: Zhang, Tianhao (VerfasserIn)
Weitere Verfasser: Chen, Zhihui, Zhang, Weifeng, Wang, Liping, Yu, Gui
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article Review fluorinated conjugated polymers fluorination strategies organic electronic device application organic field‐effect transistors polymeric semiconductors
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520 |a In recent years, conjugated polymers have received widespread attention due to their characteristic advantages of light weight, favorable solution processability, and structural modifiability. Among various conjugated polymers, fluorinated ones have developed rapidly to achieve high-performance n-type or ambipolar polymeric semiconductors. The uniqueness of fluorinated conjugated polymers contains the high coplanarity of their structures, lower frontier molecular orbital energy levels, and strong nonbonding interactions. In this review, first the fluorinated building blocks, including fluorinated benzene and thiophene rings, fluorinated B←N bridged units, and fluoroalkyl side chains are summarized. Subsequently, different synthetic methods of fluorinated conjugated polymers are described, with a special focus on their respective advantages and disadvantages. Then, with these numerous fluorinated structures and appropriate synthetic methods bear in mind, the properties and applications of the fluorinated conjugated polymers, such as cyclopentadithiophene-, amide-, and imide-based polymers, and B←N embedded polymers, are systematically discussed. The introduction of fluorine atoms can further enhance the electron-deficiency of the backbone, influencing the charge carrier transport performance. The promising fluorinated conjugated polymers are applied widely in organic field-effect transistors, organic solar cells, organic thermoelectric devices, and other organic opto-electric devices. Finally, the outlook on the challenges and future development of fluorinated conjugated polymers is systematically discussed 
650 4 |a Journal Article 
650 4 |a Review 
650 4 |a fluorinated conjugated polymers 
650 4 |a fluorination strategies 
650 4 |a organic electronic device application 
650 4 |a organic field‐effect transistors 
650 4 |a polymeric semiconductors 
700 1 |a Chen, Zhihui  |e verfasserin  |4 aut 
700 1 |a Zhang, Weifeng  |e verfasserin  |4 aut 
700 1 |a Wang, Liping  |e verfasserin  |4 aut 
700 1 |a Yu, Gui  |e verfasserin  |4 aut 
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