rGO/ZIF-8 Aerogel for Effective Removal of Malachite Green from Wastewater

In this study, dopamine-modified graphene aerogel (DGA) is synthesized through a one-step hydrothermal method using graphene oxide as the precursor and dopamine as the reducing agent. Subsequently, in situ immersion synthesis is conducted to obtain ZIF-8 loaded on a dopamine-modified graphene aeroge...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1985. - 40(2024), 24 vom: 18. Juni, Seite 12553-12564
1. Verfasser: Li, Yuling (VerfasserIn)
Weitere Verfasser: Liu, Zhuang, Gao, Bo, Mao, Luyun, Xie, Zhenbo, Han, Haoyuan, Duan, Dongchen, Fu, Haiyang, Kamali, Ali Reza
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a In this study, dopamine-modified graphene aerogel (DGA) is synthesized through a one-step hydrothermal method using graphene oxide as the precursor and dopamine as the reducing agent. Subsequently, in situ immersion synthesis is conducted to obtain ZIF-8 loaded on a dopamine-modified graphene aerogel skeleton (ZDGA), featuring a regular honeycomb interconnected mesoporosity and a high specific surface area of 532.8 m2/g. The synthesized ZDGA exhibited exceptional adsorption performance for the cationic dye malachite green. At room temperature, ZDGA achieved an impressive equilibrium adsorption capacity of 6578.34 mg/g. The adsorption process followed pseudo-secondary kinetics and adhered to the Langmuir model, indicating chemically dominated adsorption on a monomolecular layer. Intraparticle diffusion was the primary rate determinant, with π-π stacking, electrostatic adsorption, hydrogen bonding, and Lewis acid-base interactions serving as the key driving forces. It has an ideal specific surface area and good cycling performance, which highlights its potential application in dye wastewater treatment 
650 4 |a Journal Article 
700 1 |a Liu, Zhuang  |e verfasserin  |4 aut 
700 1 |a Gao, Bo  |e verfasserin  |4 aut 
700 1 |a Mao, Luyun  |e verfasserin  |4 aut 
700 1 |a Xie, Zhenbo  |e verfasserin  |4 aut 
700 1 |a Han, Haoyuan  |e verfasserin  |4 aut 
700 1 |a Duan, Dongchen  |e verfasserin  |4 aut 
700 1 |a Fu, Haiyang  |e verfasserin  |4 aut 
700 1 |a Kamali, Ali Reza  |e verfasserin  |4 aut 
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