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240521s2024 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202402412
|2 doi
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|a eng
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|a Sun, Qingde
|e verfasserin
|4 aut
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|a Critical Review of Cu-Based Hole Transport Materials for Perovskite Solar Cells
|b From Theoretical Insights to Experimental Validation
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|c 2024
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|a Text
|b txt
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|a ƒaComputermedien
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|a ƒa Online-Ressource
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|a Date Revised 01.08.2024
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2024 Wiley‐VCH GmbH.
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|a Despite the remarkable efficiency of perovskite solar cells (PSCs), long-term stability remains the primary barrier to their commercialization. The prospect of enhancing stability by substituting organic transport layers with suitable inorganic compounds, particularly Cu-based inorganic hole-transport materials (HTMs), holds promise due to their high valence band maximum (VBM) aligning with perovskite characteristics. This review assesses the advantages and disadvantages of these five types of Cu-based HTMs. Although Cu-based binary oxides and chalcogenides face narrow bandgap issues, the "chemical modulation of the valence band" (CMVB) strategy has successfully broadened the bandgap for Cu-based ternary oxides and chalcogenides. However, Cu-based ternary oxides encounter challenges with low mobility, and Cu-based ternary chalcogenides face mismatches in VBM alignment with perovskites. Cu-based binary halides, especially CuI, exhibit excellent properties such as wider bandgap, high mobility, and defect tolerance, but their stability remains a concern. These limitations of single anion compounds are insightfully discussed, offering solutions from the perspective of practical application. Future research can focus on Cu-based composite anion compounds, which merge the advantages of single anion compounds. Additionally, mixed-cation chalcogenides such as CuxM1-xS enable the customization of HTM properties by selecting and adjusting the proportions of cation M
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|a Journal Article
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|a Review
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|a copper chalcogenides
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|a copper halides
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|a copper oxides
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|a inorganic hole transport materials
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|a perovskite solar cells
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|a Sadhu, Anupam
|e verfasserin
|4 aut
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1 |
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|a Lie, Stener
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Wong, Lydia Helena
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 31 vom: 01. Aug., Seite e2402412
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g volume:36
|g year:2024
|g number:31
|g day:01
|g month:08
|g pages:e2402412
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|u http://dx.doi.org/10.1002/adma.202402412
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