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|a 10.1021/acs.langmuir.4c00823
|2 doi
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|a DE-627
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|a eng
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|a Yuan, Hang
|e verfasserin
|4 aut
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|a Bioinspired Colorimetric Double Inverse Opal Photonic Crystal Indicators for Ethanol Concentration Sensing in Fermentation Engineering
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|c 2024
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|a Text
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|a ƒaComputermedien
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|a Date Revised 28.05.2024
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a Photonic crystal-based ethanol concentration indicators with rapid response and brilliant structural color output definitely take a place in colorimetric sensors. Here, based on the H-bond-regulated swelling of acrylate shape memory polymers (SMPs) and the solvent-induced structural color change of the double inverse opal photonic crystals (DIOPCs), new-type photonic crystals (PCs) colorimetric indicators were constructed, exhibiting a span of maximum reflection wavelength (λmax) up to ∼166 nm in response to alcohols with concentrations from 0 to 100 vol %. DIOPC indicators (DIOPCIs) show a rapid response to alcohols (<1.5 s) and output different structural colors (covering from blue to red). The colorimetric sensing mechanism includes the solvent-triggered recovery of the inverse opal skeleton, the cosolvency effect and H-bonds induced swelling/shrinkage of the polymer, the phase separation between polystyrene (PS) microsphere and polymer skeleton, and the light diffraction of DIOPCs. While ensuring a larger λmax span by regulating the H-bond interactions in polymer chains through acrylamide (AAm), AAm-modified DIOPCIs are sensitive to some specific ethanol concentrations. The real-time sensing of ethanol concentration during fermentation verified the practicability of DIOPCIs, thus establishing a visual model between structural color and corresponding fermentation kinetics. We envisage that the DIOPCIs will contribute to the intelligentization of the alcoholic fermentation and distillation industry
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|a Journal Article
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|a Qi, Yong
|e verfasserin
|4 aut
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|a Niu, Wenbin
|e verfasserin
|4 aut
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|a Ma, Wei
|e verfasserin
|4 aut
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|a Zhang, Shufen
|e verfasserin
|4 aut
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|i Enthalten in
|t Langmuir : the ACS journal of surfaces and colloids
|d 1992
|g 40(2024), 21 vom: 28. Mai, Seite 11184-11195
|w (DE-627)NLM098181009
|x 1520-5827
|7 nnns
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|g volume:40
|g year:2024
|g number:21
|g day:28
|g month:05
|g pages:11184-11195
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|u http://dx.doi.org/10.1021/acs.langmuir.4c00823
|3 Volltext
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