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240512s2024 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202404172
|2 doi
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|a pubmed24n1482.xml
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|a (NLM)38734973
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|a DE-627
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|c DE-627
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|a eng
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|a Du, Kai
|e verfasserin
|4 aut
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|a High-Entropy Prussian Blue Analogues Enable Lattice Respiration for Ultrastable Aqueous Aluminum-Ion Batteries
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|c 2024
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
|b c
|2 rdamedia
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|a ƒa Online-Ressource
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|2 rdacarrier
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|a Date Revised 25.07.2024
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2024 The Author(s). Advanced Materials published by Wiley‐VCH GmbH.
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|a Aqueous aluminum ion batteries (AAIBs) hold significant potential for grid-scale energy storage owing to their intrinsic safety, high theoretical capacity, and abundance of aluminum. However, the strong electrostatic interactions and delayed charge compensation between high-charge-density aluminum ions and the fixed lattice in conventional cathodes impede the development of high-performance AAIBs. To address this issue, this work introduces, for the first time, high-entropy Prussian blue analogs (HEPBAs) as cathodes in AAIBs with unique lattice tolerance and efficient multipath electron transfer. Benefiting from the intrinsic long-range disorder and robust lattice strain field, HEPBAs enable the manifestation of the lattice respiration effect and minimize lattice volume changes, thereby achieving one of the best long-term stabilities (91.2% capacity retention after 10 000 cycles at 5.0 A g-1) in AAIBs. Additionally, the interaction between the diverse metal atoms generates a broadened d-band and reduced degeneracy compared with conventional Prussian blue and its analogs (PBAs), which enhances the electron transfer efficiency with one of the best rate performance (79.2 mAh g-1 at 5.0 A g-1) in AAIBs. Furthermore, exceptional element selectivity in HEPBAs with unique cocktail effect can facile tune electrochemical behavior. Overall, the newly developed HEPBAs with a high-entropy effect exhibit promising solutions for advancing AAIBs and multivalent-ion batteries
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|a Journal Article
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|a aqueous aluminum‐ion battery
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|a high entropy material
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|a lattice respiration
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1 |
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|a Liu, Yujie
|e verfasserin
|4 aut
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1 |
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|a Zhao, Yiqi
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Li, Hui
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Liu, Hexiong
|e verfasserin
|4 aut
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1 |
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|a Sun, Chunhao
|e verfasserin
|4 aut
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1 |
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|a Han, Mingshan
|e verfasserin
|4 aut
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| 700 |
1 |
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|a Ma, Tianyi
|e verfasserin
|4 aut
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| 700 |
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|a Hu, Yuxiang
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 30 vom: 06. Juli, Seite e2404172
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g volume:36
|g year:2024
|g number:30
|g day:06
|g month:07
|g pages:e2404172
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|u http://dx.doi.org/10.1002/adma.202404172
|3 Volltext
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