Hydroxide-Derived Nanostructures : Scalable Synthesis, Characterization, Properties, and Potential Applications

© 2024 Wiley‐VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 36(2024), 28 vom: 09. Juli, Seite e2402012
1. Verfasser: Badr, Hussein O (VerfasserIn)
Weitere Verfasser: Barsoum, Michel W
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article Review 1D nanofilaments MnO2 birnessite bottom‐up synthesis ferrite nanoparticles large scale synthesis lepidocrocite titanate self‐assembly solution‐precipitation titanium oxide
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520 |a Metal oxide nanostructures have received an increasing attention owing to their unique chemical and physical properties along with their widespread applications in various fields. This article provides an overview of the recent discovery - christened Hydroxides-Derived Nanostructures, or HDNs - in which hydroxide aqueous solutions (mostly tetramethylammonium hydroxide, TMAH) are reacted at temperatures < 100 °C and under atmospheric pressure with various metal-containing precursors to scalably prepare novel metal oxide nanostructures. In one case, a dozen commercial and earth abundant Ti-containing powders such as binary carbides, nitrides, borides, among others, are converted into new, 1D TiO2-based lepidocrocite (1DL) nanofilaments (NFs). Application-wise, the 1DLs show outstanding performance in a number of energy, environmental, and biomedical fields such as photo- and electrocatalysis, water splitting, lithium-sulfur and lithium-ion batteries, water purification, dye degradation, cancer therapy, and polymer composites. In addition to 1DL, the HDNs family encompasses other metal oxides nanostructures including magnetic Fe3O4 nanoparticles and MnO2 birnessite-based crystalline 2D flakes. The latter showed promise in electrochemical energy conversion and storage applications. The developed recipe provides a new vista in the molecular self-assembly synthesis of nanomaterials that can advance the field with a library of novel nanostructures with substantial implications in a multitude of fields 
650 4 |a Journal Article 
650 4 |a Review 
650 4 |a 1D nanofilaments 
650 4 |a MnO2 birnessite 
650 4 |a bottom‐up synthesis 
650 4 |a ferrite nanoparticles 
650 4 |a large scale synthesis 
650 4 |a lepidocrocite titanate 
650 4 |a self‐assembly 
650 4 |a solution‐precipitation 
650 4 |a titanium oxide 
700 1 |a Barsoum, Michel W  |e verfasserin  |4 aut 
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773 1 8 |g volume:36  |g year:2024  |g number:28  |g day:09  |g month:07  |g pages:e2402012 
856 4 0 |u http://dx.doi.org/10.1002/adma.202402012  |3 Volltext 
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