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240505s2024 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202401909
|2 doi
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|a pubmed24n1474.xml
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|a eng
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|a Hu, Lei
|e verfasserin
|4 aut
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|a Fusion Bonding Technique for Solvent-Free Fabrication of All-Solid-State Battery with Ultrathin Sulfide Electrolyte
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|c 2024
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|a Text
|b txt
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Revised 18.07.2024
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2024 Wiley‐VCH GmbH.
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|a For preparing next-generation sulfide all-solid-state batteries (ASSBs), the solvent-free manufacturing process has huge potential for the advantages of economic, thick electrode, and avoidance of organic solvents. However, the dominating solvent-free process is based on the fibrillation of polytetrafluoroethylene, suffering from poor mechanical property and electrochemical instability. Herein, a continuously solvent-free paradigm of fusion bonding technique is developed. A percolation network of thermoplastic polyamide (TPA) binder with low viscosity in viscous state is constructed with Li6PS5Cl (LPSC) by thermocompression (≤5 MPa), facilitating the formation of ultrathin LPSC film (≤25 µm). This composite sulfide film (CSF) exhibits excellent mechanical properties, ionic conductivity (2.1 mS cm-1), and unique stress-dissipation to promote interface stabilization. Thick LiNi0.83Co0.11Mn0.06O2 cathode can be prepared by this solvent-free method and tightly adhered to CSF by interfacial fusion of TPA for integrated battery. This integrated ASSB shows high-energy-density feasibility (>2.5 mAh cm-2 after 1400 cycles of 9200 h and run for more than 10 000 h), and energy density of 390 Wh kg-1 and 1020 Wh L-1. More specially, high-voltage bipolar cell (≥8.5 V) and bulk-type pouch cell (326 Wh kg-1) are facilely assembled with good cycling performance. This work inspires commercialization of ASSBs by a solvent-free method and provides beneficial guiding for stable batteries
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|a Journal Article
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|a bipolar and pouch cells
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|a fusion bonding
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|a solvent‐free
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|a stress‐dissipation
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|a sulfide all‐solid‐state batteries
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|a Ren, Yulang
|e verfasserin
|4 aut
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|a Wang, Ciwei
|e verfasserin
|4 aut
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|a Li, Jiedong
|e verfasserin
|4 aut
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|a Wang, Zehai
|e verfasserin
|4 aut
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|a Sun, Fu
|e verfasserin
|4 aut
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|a Ju, Jiangwei
|e verfasserin
|4 aut
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|a Ma, Jun
|e verfasserin
|4 aut
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|a Han, Pengxian
|e verfasserin
|4 aut
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|a Dong, Shanmu
|e verfasserin
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|a Cui, Guanglei
|e verfasserin
|4 aut
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 29 vom: 16. Juli, Seite e2401909
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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|g volume:36
|g year:2024
|g number:29
|g day:16
|g month:07
|g pages:e2401909
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|u http://dx.doi.org/10.1002/adma.202401909
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