Flexible Aluminum-Air Battery Based on High-Performance Three-Dimensional Dual-Network PVA/KC/KOH Composite Gel Polymer Electrolyte

With a large theoretical capacity and high energy density, aluminum-air batteries are a promising energy storage device. However, the rigid structure and liquid electrolyte of a traditional aluminum-air battery limit its application potential in the field of flexible electronics, and the irreversibl...

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Veröffentlicht in:Langmuir : the ACS journal of surfaces and colloids. - 1992. - 40(2024), 19 vom: 14. Mai, Seite 9999-10007
1. Verfasser: Zou, Chang (VerfasserIn)
Weitere Verfasser: Chen, Li, Liu, Qingye, Lu, Wei, Sun, Xueyan, Liu, Jun, Lei, Yuan, Zhao, Wei, Liu, Yilun
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Langmuir : the ACS journal of surfaces and colloids
Schlagworte:Journal Article
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520 |a With a large theoretical capacity and high energy density, aluminum-air batteries are a promising energy storage device. However, the rigid structure and liquid electrolyte of a traditional aluminum-air battery limit its application potential in the field of flexible electronics, and the irreversible corrosion of its anode greatly reduces the battery life. To solve the above problems, a PVA/KC/KOH (2 M) composite gel polymer electrolyte (GPE) with a three-dimensional dual-network structure consisting of polyvinyl alcohol (PVA), kappa-carrageenan (KC), and potassium hydroxide was prepared in this paper by a simple two-step method and applied in aluminum-air batteries. At room temperature, the ionic conductivity of the PVA/KC/KOH (2 M) composite GPE was found to be up to 6.50 × 10-3 S cm-1. By utilizing this composite GPE, a single flexible aluminum-air battery was assembled and achieved a maximum discharge voltage of 1.2 V at 5 mA cm-2, with discharge time exceeding 3 h. Moreover, the single flexible aluminum-air battery maintains good electrochemical performance under various deformation modes, and the output voltage of the battery remains at about 99% after 300 cycles. The construction of flexible aluminum-air batteries based on a three-dimensional dual-network PVA/KC/KOH composite GPE provides excellent safety and high-multiplication capabilities for aluminum-air batteries, making them potential candidates for various flexible device applications 
650 4 |a Journal Article 
700 1 |a Chen, Li  |e verfasserin  |4 aut 
700 1 |a Liu, Qingye  |e verfasserin  |4 aut 
700 1 |a Lu, Wei  |e verfasserin  |4 aut 
700 1 |a Sun, Xueyan  |e verfasserin  |4 aut 
700 1 |a Liu, Jun  |e verfasserin  |4 aut 
700 1 |a Lei, Yuan  |e verfasserin  |4 aut 
700 1 |a Zhao, Wei  |e verfasserin  |4 aut 
700 1 |a Liu, Yilun  |e verfasserin  |4 aut 
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