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240411s2024 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202401878
|2 doi
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|a pubmed24n1453.xml
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|a eng
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1 |
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|a Qi, Meiling
|e verfasserin
|4 aut
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| 245 |
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|a A Rhombic 2D Conjugated Metal-Organic Framework as Cathode for High-Performance Sodium-Ion Battery
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|c 2024
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|a Text
|b txt
|2 rdacontent
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Revised 26.06.2024
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2024 Wiley‐VCH GmbH.
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|a 2D conjugated metal-organic frameworks (2D c-MOFs) have garnered significant attention as promising electroactive materials for energy storage. However, their further applications are hindered by low capacity, limited cycling life, and underutilization of the active sites. Herein, Cu-TBA (TBA = octahydroxyltetrabenzoanthracene) with large conjugation units (narrow energy gap) and a unique rhombus topology is introduced as the cathode material for sodium-ion batteries (SIBs). Notably, Cu-TBA with a rhombus topology exhibits a high specific surface area (613 m2 g-1) and metallic band structure. Additionally, Cu-TBA outperforms its hexagonal counterpart, Cu-HHTP (HHTP = 2,3,6,7,10,11-hexahydroxyltriphenylene), demonstrating superior reversible capacity (153.6 mAh g-1 at 50 mA g-1) and outstanding cyclability with minimal capacity decay even after 3000 cycles at 1 A g-1. This work elucidates a new strategy to enhance the electrochemical performance of 2D c-MOFs cathode materials by narrowing the energy gap of organic linkers, effectively expanding the utilization of 2D c-MOFs for SIBs
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|a Journal Article
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|a cathodes
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|a conjugated metal–organic frameworks (MOFs)
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|a sodium‐ion batteries
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|a Cheng, Linqi
|e verfasserin
|4 aut
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|a Wang, Heng-Guo
|e verfasserin
|4 aut
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| 700 |
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|a Cui, Fengchao
|e verfasserin
|4 aut
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| 700 |
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|a Yang, Qingyuan
|e verfasserin
|4 aut
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| 700 |
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|a Chen, Long
|e verfasserin
|4 aut
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| 773 |
0 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 26 vom: 26. Juni, Seite e2401878
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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| 773 |
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|g volume:36
|g year:2024
|g number:26
|g day:26
|g month:06
|g pages:e2401878
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|u http://dx.doi.org/10.1002/adma.202401878
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