Thermal Radiation Annealing for Overcoming Processing Temperature Limitation of Flexible Perovskite Solar Cells

© 2024 Wiley‐VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 36(2024), 27 vom: 02. Juli, Seite e2401236
1. Verfasser: Liu, Jieqiong (VerfasserIn)
Weitere Verfasser: Zhao, Zinan, Qian, Jin, Liang, Zihui, Wu, Congcong, Wang, Kai, Liu, Shengzhong Frank, Yang, Dong
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article efficiency flexible solar cell thermal radiation annealing thermal tolerance
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520 |a Common polymeric conductive electrodes, such as polyethylene terephthalate (PET) coated with indium tin oxide, face a major challenge due to their low processing-temperature limits, attributed to PET's low glass transition temperature (Tg) of (70-80 °C). This limitation significantly narrows the scope of material selection, limits the processing techniques applicable to the low Tg, and hinders the ripened technology transfer from glass substrates to them. Addressing the temperature constraints of the flexible substrates is impactful yet underexplored, with broader implications for fields beyond photovoltaics. Here, a new thermal radiation annealing methodology is introduced to address this issue. By applying the above Tg radiation annealing in conjunction with thermoelectric cooling, highly ordered molecular packing on PET substrates is successfully created, which is exclusively unachievable due to PET's low thermal tolerance. As a result, in the context of perovskite solar cells, this approach enables the circumvention of high-temperature annealing limitations of PET substrates, leading to a remarkable flexible device efficiency of 22.61% and a record fill factor of 83.42%. This approach proves especially advantageous for advancing the field of flexible optoelectronic devices 
650 4 |a Journal Article 
650 4 |a efficiency 
650 4 |a flexible 
650 4 |a solar cell 
650 4 |a thermal radiation annealing 
650 4 |a thermal tolerance 
700 1 |a Zhao, Zinan  |e verfasserin  |4 aut 
700 1 |a Qian, Jin  |e verfasserin  |4 aut 
700 1 |a Liang, Zihui  |e verfasserin  |4 aut 
700 1 |a Wu, Congcong  |e verfasserin  |4 aut 
700 1 |a Wang, Kai  |e verfasserin  |4 aut 
700 1 |a Liu, Shengzhong Frank  |e verfasserin  |4 aut 
700 1 |a Yang, Dong  |e verfasserin  |4 aut 
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773 1 8 |g volume:36  |g year:2024  |g number:27  |g day:02  |g month:07  |g pages:e2401236 
856 4 0 |u http://dx.doi.org/10.1002/adma.202401236  |3 Volltext 
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