|
|
|
|
| LEADER |
01000caa a22002652 4500 |
| 001 |
NLM370865782 |
| 003 |
DE-627 |
| 005 |
20240704232036.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
240410s2024 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202311031
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1460.xml
|
| 035 |
|
|
|a (DE-627)NLM370865782
|
| 035 |
|
|
|a (NLM)38597244
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Gutiérrez-Armayor, David
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Simple Sol-Gel Protein Stabilization toward Rainbow and White Lighting Devices
|
| 264 |
|
1 |
|c 2024
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 04.07.2024
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2024 The Authors. Advanced Materials published by Wiley‐VCH GmbH.
|
| 520 |
|
|
|a Fluorescent proteins (FPs) are heralded as a paradigm of sustainable materials for photonics/optoelectronics. However, their stabilization under non-physiological environments and/or harsh operation conditions is the major challenge. Among the FP-stabilization methods, classical sol-gel is the most effective, but less versatile, as most of the proteins/enzymes are easily degraded due to the need of multi-step processes, surfactants, and mixed water/organic solvents in extreme pH. Herein, sol-gel chemistry with archetypal FPs (mGreenLantern; mCherry) is revisited, simplifying the method by one-pot, surfactant-free, and aqueous media (phosphate buffer saline pH = 7.4). The synthesis mechanism involves the direct reaction of the carboxylic groups at the FP surface with the silica precursor, generating a positively charged FP intermediate that acts as a seed for the formation of size-controlled mesoporous FPSiO2 nanoparticles. Green-/red-emissive (single-FP component) and dual-emissive (multi-FPs component; kinetic studies not required) FP@SiO2 are prepared without affecting the FP photoluminescence and stabilities (>6 months) under dry storage and organic solvent suspensions. Finally, FP@SiO2 color filters are applied to rainbow and white bio-hybrid light-emitting diodes featuring up to 15-fold enhanced stabilities without reducing luminous efficacy compared to references with native FPs. Overall, an easy, versatile, and effective FP-stabilization method is demonstrated in FP@SiO2 toward sustainable protein lighting
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a fluorescent protein coatings
|
| 650 |
|
4 |
|a hybrid silica nanoparticles
|
| 650 |
|
4 |
|a protein lighting devices
|
| 650 |
|
4 |
|a protein stabilization
|
| 650 |
|
4 |
|a sol‐gel methodology
|
| 700 |
1 |
|
|a Atoini, Youssef
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Van Opdenbosch, Daniel
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zollfrank, Cordt
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Nieddu, Mattia
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Costa, Rubén D
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 27 vom: 02. Juli, Seite e2311031
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:36
|g year:2024
|g number:27
|g day:02
|g month:07
|g pages:e2311031
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202311031
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 36
|j 2024
|e 27
|b 02
|c 07
|h e2311031
|