Mitigating ash-related alkali and heavy metals emissions in rotary kiln through oxygen-carrier-aided combustion of waste

Copyright © 2024 Elsevier Ltd. All rights reserved.

Bibliographische Detailangaben
Veröffentlicht in:Waste management (New York, N.Y.). - 1999. - 181(2024) vom: 30. Apr., Seite 57-67
1. Verfasser: Liu, Xue (VerfasserIn)
Weitere Verfasser: Gao, Ming, Zhou, Zhihao, Duan, Lunbo
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Waste management (New York, N.Y.)
Schlagworte:Journal Article Alkali metals Heavy metals Oxygen-carrier-aided combustion Rotary kiln Waste Metals, Heavy Oxygen S88TT14065 Alkalies mehr... Coal Ash Air Pollutants
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520 |a Rotary kiln (RK) incineration technology gains prominence in waste management, aiming to reduce pollution, recover energy, and minimize waste. Oxygen-carrier (OC)-aided incineration of waste in the RK demonstrates notable benefits by enhancing oxygen distribution uniformity and facilitating fuel conversion. However, the effects of OC on ash-related alkali and heavy metals during waste incineration in the RK remain unknown. In this study, manganese ore and ilmenite as OCs are introduced into RK during waste combustion, focusing on their effects on the bottom ashes and the behavior of alkali and heavy metals. Results show that manganese ore exhibits a decreasing reactivity due to oxygen depletion during the conversion from Mn2O3 to Mn3O4, while ilmenite maintains good reactivity due to sustained enrichment of Fe2O3 on the particles even after multiple cycles in RK. The porous structure on the surface of OCs particles verifies the cyclic reaction involving oxidation by air and reduction by fuel as OCs move between the active and passive layers of the bed. The porous OCs particles offer abundant adsorption sites for K from the gaseous phase, with surface-deposited K migrating into the particles and enhancing the OCs' capacity for K adsorption. Adding OCs promotes the formation of stable, less volatile compounds of heavy metals (As, Cr, Pb, and Zn) and enhances their retention in bottom ash while ensuring the leaching toxicity remains below Chinese national standard limits. This study enhances the understanding of OCs in incineration, guiding vital references for waste management practices and environmental sustainability 
650 4 |a Journal Article 
650 4 |a Alkali metals 
650 4 |a Heavy metals 
650 4 |a Oxygen-carrier-aided combustion 
650 4 |a Rotary kiln 
650 4 |a Waste 
650 7 |a Metals, Heavy  |2 NLM 
650 7 |a Oxygen  |2 NLM 
650 7 |a S88TT14065  |2 NLM 
650 7 |a Alkalies  |2 NLM 
650 7 |a Coal Ash  |2 NLM 
650 7 |a Air Pollutants  |2 NLM 
700 1 |a Gao, Ming  |e verfasserin  |4 aut 
700 1 |a Zhou, Zhihao  |e verfasserin  |4 aut 
700 1 |a Duan, Lunbo  |e verfasserin  |4 aut 
773 0 8 |i Enthalten in  |t Waste management (New York, N.Y.)  |d 1999  |g 181(2024) vom: 30. Apr., Seite 57-67  |w (DE-627)NLM098197061  |x 1879-2456  |7 nnns 
773 1 8 |g volume:181  |g year:2024  |g day:30  |g month:04  |g pages:57-67 
856 4 0 |u http://dx.doi.org/10.1016/j.wasman.2024.04.008  |3 Volltext 
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