|
|
|
|
| LEADER |
01000caa a22002652 4500 |
| 001 |
NLM370724739 |
| 003 |
DE-627 |
| 005 |
20240704232034.0 |
| 007 |
cr uuu---uuuuu |
| 008 |
240407s2024 xx |||||o 00| ||eng c |
| 024 |
7 |
|
|a 10.1002/adma.202403078
|2 doi
|
| 028 |
5 |
2 |
|a pubmed24n1460.xml
|
| 035 |
|
|
|a (DE-627)NLM370724739
|
| 035 |
|
|
|a (NLM)38583072
|
| 040 |
|
|
|a DE-627
|b ger
|c DE-627
|e rakwb
|
| 041 |
|
|
|a eng
|
| 100 |
1 |
|
|a Yang, Binbin
|e verfasserin
|4 aut
|
| 245 |
1 |
0 |
|a Super-Ionic Conductor Soft Filler Promotes Li+ Transport in Integrated Cathode-Electrolyte for Solid-State Battery at Room Temperature
|
| 264 |
|
1 |
|c 2024
|
| 336 |
|
|
|a Text
|b txt
|2 rdacontent
|
| 337 |
|
|
|a ƒaComputermedien
|b c
|2 rdamedia
|
| 338 |
|
|
|a ƒa Online-Ressource
|b cr
|2 rdacarrier
|
| 500 |
|
|
|a Date Revised 04.07.2024
|
| 500 |
|
|
|a published: Print-Electronic
|
| 500 |
|
|
|a Citation Status PubMed-not-MEDLINE
|
| 520 |
|
|
|a © 2024 Wiley‐VCH GmbH.
|
| 520 |
|
|
|a Composite polymer solid electrolytes (CPEs), possessing good rigid flexible, are expected to be used in solid-state lithium-metal batteries. The integration of fillers into polymer matrices emerges as a dominant strategy to improve Li+ transport and form a Li+-conducting electrode-electrolyte interface. However, challenges arise as traditional fillers: 1) inorganic fillers, characterized by high interfacial energy, induce agglomeration; 2) organic fillers, with elevated crystallinity, impede intrinsic ionic conductivity, both severely hindering Li+ migration. Here, a concept of super-ionic conductor soft filler, utilizing a Li+ conductivity nanocellulose (Li-NC) as a model, is introduced which exhibits super-ionic conductivity. Li-NC anchors anions, and enhances Li+ transport speed, and assists in the integration of cathode-electrolyte electrodes for room temperature solid-state batteries. The tough dual-channel Li+ transport electrolyte (TDCT) with Li-NC and polyvinylidene fluoride (PVDF) demonstrates a high Li+ transfer number (0.79) due to the synergistic coordination mechanism in Li+ transport. Integrated electrodes' design enables stable performance in LiNi0.5Co0.2Mn0.3O2|Li cells, with 720 cycles at 0.5 C, and 88.8% capacity retention. Furthermore, the lifespan of Li|TDCT|Li cells over 4000 h and Li-rich Li1.2Ni0.13Co0.13Mn0.54O2|Li cells exhibits excellent performance, proving the practical application potential of soft filler for high energy density solid-state lithium-metal batteries at room temperature
|
| 650 |
|
4 |
|a Journal Article
|
| 650 |
|
4 |
|a composite polymer electrolyte
|
| 650 |
|
4 |
|a integrated electrode
|
| 650 |
|
4 |
|a room temperature
|
| 650 |
|
4 |
|a solid‐state lithium metal battery
|
| 650 |
|
4 |
|a super‐ionic conductor soft filler
|
| 700 |
1 |
|
|a Deng, Chenglong
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chen, Nan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhang, Fengling
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Hu, Kaikai
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Gui, Boshun
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Zhao, Liyuan
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Wu, Feng
|e verfasserin
|4 aut
|
| 700 |
1 |
|
|a Chen, Renjie
|e verfasserin
|4 aut
|
| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 27 vom: 02. Juli, Seite e2403078
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
|
| 773 |
1 |
8 |
|g volume:36
|g year:2024
|g number:27
|g day:02
|g month:07
|g pages:e2403078
|
| 856 |
4 |
0 |
|u http://dx.doi.org/10.1002/adma.202403078
|3 Volltext
|
| 912 |
|
|
|a GBV_USEFLAG_A
|
| 912 |
|
|
|a SYSFLAG_A
|
| 912 |
|
|
|a GBV_NLM
|
| 912 |
|
|
|a GBV_ILN_350
|
| 951 |
|
|
|a AR
|
| 952 |
|
|
|d 36
|j 2024
|e 27
|b 02
|c 07
|h e2403078
|