Cephalopod-Inspired Chemical-Gated Hydrogel Actuation Systems for Information 3D-Encoding Display

© 2024 Wiley‐VCH GmbH.

Bibliographische Detailangaben
Veröffentlicht in:Advanced materials (Deerfield Beach, Fla.). - 1998. - 36(2024), 25 vom: 17. Juni, Seite e2401659
1. Verfasser: Wu, Baoyi (VerfasserIn)
Weitere Verfasser: Si, Muqing, Hua, Luqin, Zhang, Dong, Li, Wanning, Zhao, Chuanzhuang, Lu, Wei, Chen, Tao
Format: Online-Aufsatz
Sprache:English
Veröffentlicht: 2024
Zugriff auf das übergeordnete Werk:Advanced materials (Deerfield Beach, Fla.)
Schlagworte:Journal Article bioinspired materials chemical‐gated actuation fluorescent patterning hydrogel information 3D‐encoding
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520 |a Cephalopods evolve the acetylcholine-gated actuation control function of their skin muscles, which enables their dynamic/static multimode display capacities for achieving perfectly spatial control over the colors/patterns on every inch of skin. Reproduction of artificial analogs that exhibit similar multimodal display is essential to reach advanced information three-dimensional (3D) encoding with higher security than the classic 2D-encoding strategy, but remains underdeveloped. The core difficulty is how to replicate such chemical-gated actuation control function into artificial soft actuating systems. Herein, this work proposes to develop azobenzene-functionalized poly(acrylamide) (PAAm) hydrogel systems, whose upper critical solution temperature (UCST) type actuation responsiveness can be intelligently programmed or even gated by the addition of hydrophilic α-cyclodextrin (α-CD) molecules for reversible association with pendant azobenzene moieties via supramolecular host-guest interactions. By employing such α-CD-gated hydrogel actuator as an analogue of cephalopods' skin muscle, biomimetic mechanically modulated multicolor fluorescent display systems are designed, which demonstrate a conceptually new α-CD-gated "thermal stimulation-hydrogel actuation-fluorescence output" display mechanism. Consequently, high-security 3D-encoding information carriers with an unprecedented combination of single-input multiple-output, dynamic/static dual-mode and spatially controlled display capacities are achieved. This bioinspired strategy brings functional-integrated features for artificial display systems and opens previously unidentified avenues for information security 
650 4 |a Journal Article 
650 4 |a bioinspired materials 
650 4 |a chemical‐gated actuation 
650 4 |a fluorescent patterning 
650 4 |a hydrogel 
650 4 |a information 3D‐encoding 
700 1 |a Si, Muqing  |e verfasserin  |4 aut 
700 1 |a Hua, Luqin  |e verfasserin  |4 aut 
700 1 |a Zhang, Dong  |e verfasserin  |4 aut 
700 1 |a Li, Wanning  |e verfasserin  |4 aut 
700 1 |a Zhao, Chuanzhuang  |e verfasserin  |4 aut 
700 1 |a Lu, Wei  |e verfasserin  |4 aut 
700 1 |a Chen, Tao  |e verfasserin  |4 aut 
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773 1 8 |g volume:36  |g year:2024  |g number:25  |g day:17  |g month:06  |g pages:e2401659 
856 4 0 |u http://dx.doi.org/10.1002/adma.202401659  |3 Volltext 
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