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|a 10.1002/adma.202312254
|2 doi
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|a pubmed24n1439.xml
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|a (DE-627)NLM370115481
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|a (NLM)38521992
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|a eng
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|a Nguyen-Dang, Tung
|e verfasserin
|4 aut
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|a Air-Stable Perylene Diimide Trimer Material for N-Type Organic Electrochemical Transistors
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|c 2024
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|a Text
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|a ƒaComputermedien
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|2 rdamedia
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|a ƒa Online-Ressource
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|a Date Revised 13.06.2024
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|a published: Print-Electronic
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|a Citation Status PubMed-not-MEDLINE
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|a © 2024 Wiley‐VCH GmbH.
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|a A new method is reported to make air-stable n-type organic mixed ionic-electronic conductor (OMIEC) films for organic electrochemical transistors (OECTs) using a solution-processable small molecule helical perylene diimide trimer, hPDI[3]-C11. Alkyl side chains are attached to the conjugated core for processability and film making, which are then cleaved via thermal annealing. After the sidechains are removed, the hPDI[3] film becomes less hydrophobic, more ordered, and has a deeper lowest unoccupied molecular orbital (LUMO). These features provide improved ionic transport, greater electronic mobility, and increased stability in air and in aqueous solution. Subsequently, hPDI[3]-H is used as the active material in OECTs and a device with a transconductance of 44 mS, volumetric capacitance of ≈250 F cm-3, µC* value of 1 F cm-1 V-1 s-1, and excellent stability (> 5 weeks) is demonstrated. As proof of their practical applications, a hPDI[3]-H-based OECTs as a glucose sensor and electrochemical inverter is utilized. The approach of side chain removal after film formation charts a path to a wide range of molecular semiconductors to be used as stable, mixed ionic-electronic conductors
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|a Journal Article
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|a mixed ionic‐electronic conductors
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|a n‐type semiconductors
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|a organic electrochemical transistors
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|a sidechain engineering
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|a small molecules
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|a Bao, Si Tong
|e verfasserin
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|a Kaiyasuan, Chokchai
|e verfasserin
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|a Li, Kunyu
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|a Chae, Sangmin
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|a Yi, Ahra
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|a Joy, Syed
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|a Harrison, Kelsey
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|a Kim, Jae Young
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|a Pallini, Francesca
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|a Beverina, Luca
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|a Graham, Kenneth R
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|a Nuckolls, Colin
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|a Nguyen, Thuc-Quyen
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| 773 |
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|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 24 vom: 02. Juni, Seite e2312254
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnns
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|g volume:36
|g year:2024
|g number:24
|g day:02
|g month:06
|g pages:e2312254
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|u http://dx.doi.org/10.1002/adma.202312254
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