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240323s2024 xx |||||o 00| ||eng c |
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|a 10.1002/adma.202400436
|2 doi
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|a pubmed25n1232.xml
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|a (DE-627)NLM370037685
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|a (NLM)38514194
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|a DE-627
|b ger
|c DE-627
|e rakwb
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| 041 |
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|a eng
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| 100 |
1 |
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|a Zhong, Chao
|e verfasserin
|4 aut
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| 245 |
1 |
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|a Bottom-Up Synthesized Glucan Materials
|b Opportunities from Applied Biocatalysis
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| 264 |
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1 |
|c 2024
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| 336 |
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|a Text
|b txt
|2 rdacontent
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| 337 |
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|a ƒaComputermedien
|b c
|2 rdamedia
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| 338 |
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|a ƒa Online-Ressource
|b cr
|2 rdacarrier
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| 500 |
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|a Date Completed 04.07.2024
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|a Date Revised 04.07.2024
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|a published: Print-Electronic
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|a Citation Status MEDLINE
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|a © 2024 The Authors. Advanced Materials published by Wiley‐VCH GmbH.
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|a Linear d-glucans are natural polysaccharides of simple chemical structure. They are comprised of d-glucosyl units linked by a single type of glycosidic bond. Noncovalent interactions within, and between, the d-glucan chains give rise to a broad variety of macromolecular nanostructures that can assemble into crystalline-organized materials of tunable morphology. Structure design and functionalization of d-glucans for diverse material applications largely relies on top-down processing and chemical derivatization of naturally derived starting materials. The top-down approach encounters critical limitations in efficiency, selectivity, and flexibility. Bottom-up approaches of d-glucan synthesis offer different, and often more precise, ways of polymer structure control and provide means of functional diversification widely inaccessible to top-down routes of polysaccharide material processing. Here the natural and engineered enzymes (glycosyltransferases, glycoside hydrolases and phosphorylases, glycosynthases) for d-glucan polymerization are described and the use of applied biocatalysis for the bottom-up assembly of specific d-glucan structures is shown. Advanced material applications of the resulting polymeric products are further shown and their important role in the development of sustainable macromolecular materials in a bio-based circular economy is discussed
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| 650 |
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4 |
|a Journal Article
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|a Review
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4 |
|a bottom‐up synthesis
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| 650 |
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4 |
|a carbohydrate‐active enzymes
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| 650 |
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4 |
|a enzyme and material bioengineering
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| 650 |
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4 |
|a hybrid biomaterials
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| 650 |
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4 |
|a oligo‐/polysaccharide materials
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| 650 |
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7 |
|a Glucans
|2 NLM
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| 650 |
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7 |
|a Glycosyltransferases
|2 NLM
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| 650 |
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7 |
|a EC 2.4.-
|2 NLM
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| 650 |
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7 |
|a Glycoside Hydrolases
|2 NLM
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| 650 |
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7 |
|a EC 3.2.1.-
|2 NLM
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| 700 |
1 |
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|a Nidetzky, Bernd
|e verfasserin
|4 aut
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| 773 |
0 |
8 |
|i Enthalten in
|t Advanced materials (Deerfield Beach, Fla.)
|d 1998
|g 36(2024), 27 vom: 21. Juli, Seite e2400436
|w (DE-627)NLM098206397
|x 1521-4095
|7 nnas
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| 773 |
1 |
8 |
|g volume:36
|g year:2024
|g number:27
|g day:21
|g month:07
|g pages:e2400436
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| 856 |
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|u http://dx.doi.org/10.1002/adma.202400436
|3 Volltext
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